This contribution provides an analysis of the basic coordination tendencies of manganese with specific emphasis on the biological chemistry of this element. The review is broken into four parts. First, a discussion of the basic coordination chemistry o f manganese is mononuclear and multinuclear environments is prescnted. Second, the biophysical data essential to the development of models for t...

The reaction of diazotetracyanocyclopentadiene with copper powder in the presence NEt4Cl yields, unexpectedly, besides known NEt4[C5H(CN)4] (3), NEt4 salt octacyanofulvalenediide (NEt4)2[C10(CN)8] (5), which can be transformed via AgNO3 to corresponding Ag+ (4), turn reacted KCl yield K+ 6. molecular and crystal structures 4–6 could determined, show a significantly twisted aromatic dianion uses...

This themed issue of Chemistry is in honor Professor Christoph Janiak on the occasion his 60th birthday, and celebrates innovative contributions to fields supramolecular chemistry, coordination polymers, networks metal-organic frameworks, inorganic/organic hybrid materials inorganic from ionic liquids [...]

Nitrogen constitutes one of the most crucial elements in synthetic compounds, both organic and coordination chemistry [...]

Coordination between boron Lewis acid and nitrogen base (B?N) is a classically chemical issue that has been known for several decades. Recently, this B?N chemistry developed into new stage toward electronic materials, e.g., adjusting optoelectronic properties of N-based conjugated molecules via adding B acids, synthesizing B?N-bridged units, further constructing B?N-embedded organic photovoltai...