A complex of N, N, N', N', -tetramethylated ethylenediamine, TMEDA, with CuCI is prepared. The crystal and molecular structure of this complex is characterized by a single-crystal X-ray diffraction study. The complex is found to contain [Cu (TMEDA) ] cation which is nearly tetrahedral and the [CuCI ) anion is linear which Cu lies on a center of symmetry. Crystals are monoclinic space grou...

Single crystals consisting various surface morphologies and epitaxial structures were applied to investigate the effect of other phase regions in the vicinity of a given tethered chains-covered area having a certain molecular weight of amorphous brushes. The designed experiments demonstrated that regardless of the type of surface morphology (patterned and especial mixed-brushes, homo and co...

A fully automatic spray-LBL machine with monitoring the real time growth of multilayer films using Quartz Crystal Microbalance (QCM) techniques was newly developed. We established fully automatic spray layer-by-layer method by precisely controlling air pressure, solution flow, and spray pattern. The movement pattern towards the substrate during solution spraying allowed fabrication of a nano-sc...

Crystal dislocations were invisible until the mid-20th century although their presence had been inferred; the atomic and molecular scale dimensions had prevented earlier discovery. Now they are normally known to be just about everywhere, for example, in the softest molecularly-bonded crystals as well as within the hardest covalently-bonded diamonds. The advent of advanced techniques of atomic-s...

The frequency response of quartz crystal microbalance loaded by single-drop liquid is studied in this paper. Previous studies have shown that the relationship between resonant frequency and properties of liquid by completely immersing one side of the crystal in liquid. In this work, only localized portion of crystal was wetted by liquid droplet. Repeated experiment shows the relationship betwee...

Quartz crystal microbalances (QCMs) in contact with liquid droplets have been used to investigate the rheological properties of liquids and the diverse solid-liquid interfacial phenomena. In this article, we first report the experimental results of the QCM responses due to the deposition of microliter droplets of silicone oils. The silicone oils with viscosity in a range from 50cS to 10cS are t...

The temperature dependence of magneto-optical and magneto-photoconductivity measurements were carried out in the range of (200-330) K. A home made optical cryostat was used for the measurements. The measured room temperature value of the energy gap was found to be 2.211 eV. The temperature coefficient of energy gap was found to be -5.48×10-4 eV/K obtained by the optical absorption method and -4...

high density polyethylene (hdpe) films were produced using cast film extrusion process with different draw ratios, ranging from 16.9 to 148.8. morphology, crystallinty and orientation state of crystalline and amorphous phases of the cast films were investigated using scanning electron microscopy (sem), differential scanning calorimetry (dsc) and polarized fourier transform infrared spectroscopy...