A rigid-flexible hybrid hydrogen-bonded organic framework (HOF) with guest-induced reversible crystallinity was designed by Yingjie Zhao and Danbo Wang in their Research Article (e202217903). specific compound, such as hexane, acts a “key” to control the crystallinity, while triangle macrocycle building module is “lock”. The introduction removal of molecule affects local flexibility whole leads...

Hierarchical SAPO-34 zeolite with high crystallinity and excellent hydrothermal stability was directly synthesized in the nanoscale confined environment provided by the natural layered material kaolin.

BACKGROUND The efficiency of enzymatic hydrolysis is reduced by the structural properties of cellulose. Although efforts have been made to explain the mechanism of enzymatic hydrolysis of cellulose by considering the interaction of cellulolytic enzymes with cellulose or the changes in the structure of cellulose during enzymatic hydrolysis, the process of cellulose hydrolysis is not yet fully un...

The two polyhydroxy surfactants polyglycerol 6-distearate (Plurol(®)Stearique WL1009 - (PS)) and caprylyl/capryl glucoside (Plantacare(®) 810 - (PL)) are a class of PEG-free stabilizers, made from renewable resources. They were investigated for stabilization of aqueous solid lipid nanoparticle (SLN) and nanostructured lipid carrier (NLC) dispersions. Production was performed by high pressure ho...

cofe2o4 have been synthesized via a surfactant assisted gel microwave route with a molar ratio of fe/co= 2 and oleic acid (oa) was used as a surfactant. fourier transform infrared spectroscopy (ftir), x-ray diffraction (xrd) and scanning electron microscopy (sem) were used to consider the structural and morphological properties of cofe2o4 nano-particles. results demonstrated that oleic acid is ...

The relationship between the solubility, crystallinity, and length of the unit chains of plant storage α-glucan was investigated by manipulating the chain length of α-glucans accumulated in a rice mutant. Transgenic lines were produced by introducing a cDNA for starch synthase IIa (SSIIa) from an indica cultivar (SSIIa (I), coding for active SSIIa) into an isoamylase1 (ISA1)-deficient mutant (i...

introduction: the aim of this study was to compare the chemical compounds of white proroot mineral trioxide aggregate (wmta) hydrated at different ph environments. methods and materials: mixed samples of wmta were kept in acidic (ph=5.4), neutral (ph=7.4) and alkaline (ph=9.4) environments for 48 h. then, x-ray diffraction (xrd) analysis was performed for both hydrated and powder forms of wmta....

Semicrystalline films of poly(vinyl alcohol) (PVA) were prepared by annealing amorphous PVA films at temperatures above the glass transition temperature of 85°C, thus allowing the macromolecules to form crystallites, which stabilized the films and made them behave as if they were chemically cross-linked. Films were prepared by casting a 15% aqueous PVA solution onto glass slides and annealing t...

Porous and bioactive polyetheretherketone (PEEK) scaffolds have potential to replace metallic scaffolds for biologic fixation of permanent implants adjacent to trabecular bone, such as interbody spinal fusion devices. The objective of this study was to investigate the effects of the mold temperature and PEEK powder on the mechanical properties and crystallinity of hydroxyapatite (HA) whisker-re...

Although measurements of crystallinity index (CI) have a long history, it has been found that CI varies significantly depending on the choice of measurement method. In this study, four different techniques incorporating X-ray diffraction and solid-state 13C nuclear magnetic resonance (NMR) were compared using eight different cellulose preparations. We found that the simplest method, which is al...