A series of new cationic dioxidomolybdenum(VI) complexes [MoO2(Ln)]PF6 (2–5) with the tripodal tetradentate pyridyl aminophenolate ligands HL2-HL5 have been synthesized and characterized. Ligands HL2-HL4 carry substituents in 4-position phenolate ring, viz. Cl, Br NO2, respectively, whereas ligand HL5, N-(2-hydroxy-3,5-di-tert-butylbenzyl)-N,N-bis(2-pyridylmethyl)amine, is a derivative 3,5-di-t...

AB diblock copolymers were prepared by sequential ring-opening metathesis polymerization of cyclooctenes catalyzed by a Ru-based Grubbs catalyst. The relatively slow polymerization of cis-3-phenylcyclooct-1-ene (3PC) or cis-cyclooct-2-en-1-yl acetate (3AC) was first carried out and then followed by the faster polymerization of unsubstituted cis-cyclooctene (COE) from the active Ru-alkylidene ch...

A critical limitation of bioorthogonal click chemistry for in vivo applications has been its low reaction efficiency due to the pharmacokinetic barriers, such as blood distribution, circulation, and elimination in living organisms. To identify key factors that dominate the efficiency of click chemistry, here a rational design of near-infrared fluorophores containing tetrazine as a click moiety ...

long–term stability and oxidation resistance of aisi 439 ferritic stainless steel used as interconnects in solid oxide fuel cells can be improved by use of a protective coating. in this study the pack cementation method was employed to coat aisi 439 ferritic stainless steel with manganese. isothermal oxidation was conducted at 800 ºc for 200 hours in static air to investigate the role of coatin...

a general overview on the prospective of various oxidation and combined processes in the treatment of tannery industry effluent are reported. various oxidation and combined processes such as uv/h2o2/hypochlorites, fenton and electro-oxidation, photo-chemical, photo-catalytic, electro-catalytic oxidation, wet air oxidation, ozonation, biological followed by ozone/uv/ h2o2, coagulation or ele...

The oxidative decarbonylation of the η(3)-allyl dicarbonyl complexes [Mo(η(3)-C(3)H(5))Cl(CO)(2)(L)] (L = 2,2'-bipyridine (bipy) (1), 4,4'-di-tert-butyl-2,2'-bipyridine (di-tBu-bipy) (2)) by reaction with aqueous tert-butylhydroperoxide (TBHP) or H(2)O(2) gave the following compounds in good to excellent yields: the oxo-bridged dimers [MoO(2)Cl(L)](2)O (L = bipy (3), di-tBu-bipy (6)) using TBHP...