Biopolymer/inorganic material nanocomposites have attracted increasing interest as nanocarriers for delivering drugs owing to the combined advantages of both biopolymer and inorganic materials. Here, amphiphilic block copolymer/fullerene nanocomposites were prepared as nanocarriers for hydrophobic drug by incorporation of C60 in the core of methoxy polyethylene glycol-poly(d,l-lactic acid) (MPE...

The design of multicomponent ionic complexes of fullerenes, (D1) (C60 ) (D2) is discussed. In this approach D1 was an organic cation and D2 was a neutral structure-forming molecule. These complexes demonstrated paramagnetic-diamagnetic transitions associated with the C-C and M-C bond formation, singlet-triplet transitions and high conductivity. 1. (D) (C60 ) CoOEP contain tetramethylphosphonium...

It is shown that the free energy of C2v clusters favors a transformation from a closed cage (fullerene) structure at low temperatures to a more open corrannulene structure and then to a ring structure as the temperature is increased. The corrannulene structure can be thought of as a fragment of C60 and is an efficient precursor to its formation. These results are applicable to other carbon clus...

The aim of this study is to develop a bias-correction method for realized variance (RV) estimation, where the equilibrium price process is contaminated with market microstructure noise, such as bid-ask bounces and price changes discreteness. Though RV constitutes the simplest estimator of daily integrated variance, it remains strongly biased and many estimators proposed in previous studies requ...

A new, highly flexible porphyrin dimer was isolated in preparative scale from a dynamic disulfide library; this receptor adjusts to fit guests with a wide range of steric requirements and, whilst C60 proved to be an unsuitable template for this library, a new C60-porphyrin complex was isolated and characterised.

To explore the distinction between state dependence and heterogeneity in repeated decisions, this paper combines a Mixed Logit model with a state dependence parameterization from the marketing literature to study fishing location choices of commercial sea urchin divers in California. It examines implications of ignoring either effect and finds in all cases that true state dependence is an impor...

Geometrically defined C60 self-assembled disks, wires and dots have been systematically obtained via a solution drop-drying process at room temperature; during this process, we discovered that there is a critical correlation between the geometry of the solvent and the final geometry of the self-assembled C60 structure.

Heterogeneity, State Dependence and Health We investigate the evolution of health over the life-cycle. We allow for two sources of persistence: unobserved heterogeneity and state dependence. Estimation indicates that there is a large degree of heterogeneity. For half the population, there are modest degrees of state dependence. For the other half of the population, the degree of state dependenc...

Dependence Measures in Bivariate Gamma Frailty Models Bivariate duration data frequently arise in economics, biostatistics and other areas. In “bivariate frailty models”, dependence between the frailties (i.e., unobserved determinants) induces dependence between the durations. Using notions of quadrant dependence, we study restrictions that this imposes on the implied dependence of the duration...

In this paper, we investigate the asymmetry in the tail dependence between US equity portfolios and the aggregate US market. Given the limited number of observations in the tails of a joint distribution, standard non-parametric measures of tail dependence often have poor finite-sample properties. We therefore develop a parametric model for measuring and testing asymmetry in tail dependence, usi...