In this work, a series of polyoxometalates (POMs), as soluble salts formula Sn1.5PMo12O40, SbPMo12O40 and H 3-x Sn x1 Sb x2 PMo 12 O 40 (x=2x 1 +3x 2 x , = 0–0.75) were synthesized using the cationic exchange method under stoichiometric conditions. They characterized tested in oxidation cyclohexanone hydrogen peroxide absence organic solvent, co-catalyst phase transfer compounds or surfactants....

a new cesium ion selective pvc membrane based on parent calix [4] arene was developed for potentiometric determination of cesium in environmental samples. the electrode based on p-5,11,17,23tetra(tertbutyl) 25,26,27,28-tetrahydroxy calix[4]arene(thc) as ionophor ,dibutyl phthalate (dbp)as plasticizer ,sodium tetra phenyl borate(natpb)and oleic acid as lipophilic salt and additive showed the bes...

In this paper, the carbon paste electrode (CPE) is modified using an ionic liquid (1-Butyl-3-methylimidazolium tetrafluoroborate, [BMIM]BF4) and the cis-dioxo-bis[3-methoxy-2,2-dimethylpropanediamine] molybdenum(VI) complex (cis-[Mo(O)2L]). In order to study of the electrochemical behavior of ascorbic acid (AA) and dopamine (DA) at the surface of the prepared CPEs, the differential pulse and cy...

Background & Aims of the Study: Since the chromium (VI) is a toxic, carcinogenic and non-biodegradable element and can accumulate in the tissues, the presence and release of this element through the effluents is associated with dangerous effects on life cycle. Thus, it should be removed from the effluents. In the present study, biosorption of Cr(VI) from aqueous solutio...

A rapid, reliable and accurate method for the determination of hexavalent chromium in Portland cement is developed. The proposed method includes direct spectrophotometric determination of Cr (VI) in Portland cement with 1, 2, 5, 8 Tetrahydroxyanthraquinone, (Quinalizarin, QINZ) at pH 1.5. The European Directive (2003/53/EC) limits the use of cements so that it contains no more than 2 mg·Kg of w...

polarographic methods have been developed for the determination of two cephalosporins namely cefotaxime (ctx) and ceftriaxone (ctr) in pharmaceutical formulations. well defined peaks at potentials –1.432 v vs. sce for ctx and –1.627 v vs. sce for ctr were obtained in the presence of tungsten (vi). the method has been successfully applied for the determination of above mentioned cephalosporins i...

MoDTC molecular additives reduce friction in boundary lubricated steel-steel contacts through formation of MoS2 sheets. The chemical pathway from to is investigated for optimizing formation. Our experiments show that a molecule containing sulfur only its thiocarbamate ligands forms sheets during friction, demonstrating the presence peripheral can be sufficient provide required source. This not ...