BACKGROUND Eugenol, the main constituent of clove oil possesses a number of medicinal activities. To enhance the medicinal property, structural modification is required. On the other hand, bismuth nitrate pentahydrate has been established as an excellent eco-friendly nitrating agent for several classes of organic compounds. RESULTS Bismuth nitrate pentahydrate-induced nitration of eugenol has...

The use of natural resources as a chemical feedstock for the synthesis of added-value products is gaining interest; as such we report an environmentally friendly method for the synthesis of para-menthane-3,8-diol from natural citronellal oil in 96% yield, under solvent free aqueous conditions. The acylation of para-menthane-3,8-diol with various acid anhydrides over polymer-supported scandium t...

the synthesis of functionalized 2-oxo-2h-coumarin derivatives has been studied by a one-pot reaction of o-hydroxybenzaldehyde, ethyl 2-bromoacetate and triphenylphosphine in the presence of catalytic amount of triethyl amine in etoac, water or under solvent free conditions. we have found the best results obtained under solvent free condition.

a series of tri- and tetra- substituted imidazoles were synthesized from benzyl, aldehyde and ammonium acetate in the presence of zeolite as an ecofriendly reusable catalyst under microwave irradiation in the absence of solvent. the yields are high to excellent and the use of microwave irradiation reduces reaction times to few minute.

a rapid and efficient one-pot, four-component protocol towards the synthesis of polyhydroquinoline derivatives has been developed. the condensation of aldehyde, dimedone, ethyl acetoacetate and ammonium acetate in presence of stannous chloride was carried out under solvent free condition to synthesize a variety of polyhydroquinoline derivatives in good to excellent yields. stannous chloride was...

objective(s): the development of reliable and ecofriendly process for the synthesis of nano-metals is an important aspect in the field of nanotechnology. nano-metals are a special group of materials with broad area of applications. materials and methods: in this study, extracellular synthesis of silver nanoparticles (snps) performed by use of the gram positive soil streptomycetes. streptomycete...

to enhance solubility and the performance of a plant gum (from south peach tree of china, sp gum) as a drilling fluid additive, we explored the potential of modified sp (msp) gum by modifying it with epichlorohydrin. the modification conditions, such as the mass ratio of  the crosslinking agent, ph and temperature, were optimized and the results show that 56.40 g/100g mass ratio of the crosslin...