a poly(vinyl chloride) membrane based on a new a-dioxime derivative as membrane carrier was prepared andinvestigated as a cr(iii) selective electrode. the electrode exhibits a good potentiometric response for cr(iii)over a wide concentration range 1.0 x 10-6 to 1.0 x 10-1 m with a slope 19.5+0.5 mv/decade and low detectionlimit of 8.9 x 10-7 m. it has a fast response time < 15 s. the best perfo...

vanadium is quantitatively retained on 2-nitroso-1-naphhthol-4-sulfonic acid tetradecyldimethlbenzyammonium chloride onto microcrystalline naphthalene in the ph range of 3.0-4.0 from a large volume of aqueous solutions of various alloys and synthetic samples. after filtration, the solid mass consisting of the vanadium complex and naphthalene was dissolved with 5.0 ml of dimethylformamide and th...