The photoelectron spectrum of the anilinide ion has been measured. The spectrum exhibits a vibrational progression of the CCC in-plane bending mode of the anilino radical in its electronic ground state. The observed fundamental frequency is 524 ± 10 cm(-1). The electron affinity (EA) of the radical is determined to be 1.607 ± 0.004 eV. The EA value is combined with the N-H bond dissociation ene...

This paper uses field theory to derive the exact dispersion relation of space charge waves in a two-dimensional electron gas (2DEG) located dielectric or dissimilar waveguide. It is found that 2DEG can be modeled accurately using free-electron sheet model, which further confirmed by almost identical polarizability and with zero drift velocity. Transitions among well-known dispersion, beam mode ...

A bstract We point out that neutrinos can have enhanced couplings to photons, if light (pseudo)scalar mediators are present, resulting in a potentially measurable neutrino polarizability. show the expected suppression from small masses be compensated by mediator mass, generating dimension 7 Rayleigh operators at low scales. explore rich phenomenology of such models, computing detail constraints...

in this study, we present the work on the physicochemical interaction between the anti-cancer alkaloidberberine (brb) and dna with the purpose of designing drugs that interact more with dna. molecularmodeling on the complex formed between berberine and dna presented that this complex was undeniablyfully able of participating in the formation of a stable intercalation site. besides, the molecula...

We describe how the out-of-plane dielectric polarizability of monolayer graphene influences electrostatics bilayer graphene—both Bernal (BLG) and twisted (tBLG). compare value computed using density functional theory with output from previously published experimental data on electrostatically controlled interlayer asymmetry potential in BLG on-layer distribution tBLG. show that monolayers tBLG ...

The potential energy curves, permanent and transition dipole moments, and the static dipolar polarizability, of molecular ions composed of one alkali-metal atom and a strontium ion are determined with a quantum chemistry approach. The molecular ions are treated as effective two-electron systems and are treated using effective core potentials including core polarization, large gaussian basis set...

Molecular R-matrix with pseudostate calculations are reported for the electron-impact ionization cross section of the carbon dimer anion. A (1)Sigma_(g)(+) resonance is found near the detachment threshold and two further resonances, of (3)Pi_(g) and (1)Pi_(g) symmetry, are found near 10 eV close to the structures observed experimentally. These unusual shape resonances are a result of the compet...

The coupling of electronic transitions within molecules to condensed-phase media involves a complex hierarchy of spatial and dynamical scales. Thermodynamics of activation is related to the length scale of microscopic interactions reflected in the non-Arrhenius reaction kinetics. Solvent dynamics make a particularly strong impact on the activation barrier when the time scale of the reaction is ...