In experiments at 600°C in the system NaCI-KCI-H20, within the analytical uncertainty, stoichiometric quantities of C1 and total alkali metals (Na+K) appear to dissolve in steam coexisting with chloride-rich brine at high pressures in the absence of solid salt. In contrast, at lower pressures, where steam coexists with precipitated salts, significant excess chloride as associated hydrogen chlor...