The 24 components of the relativistic spin tensor consist of 3 + 3 basic spin fields and 9 + 9 constitutive fields. Empirically only 3 basic spin fields and 9 constitutive fields are known. This empirem can be expressed by two spin axioms, one of them identifying 3 spin fields, and the other one 9 constitutive fields to each other. This identification by the spin axioms is material-independent ...

We construct arbitrary matrix elements of the quantum evolution operator for a wide class of self-adjoint canonical Hamiltonians, including those which are polynomial in the Heisenberg operators, as the limit of well defined path integrals involving Wiener measure on phase space, as the diffusion constant diverges. A related construction achieves a similar result for an arbitrary spin Hamiltonian.

First-principles calculations of the spin-orbit coupling in graphene with hydrogen adatoms in dense and dilute limits are presented. The chemisorbed hydrogen induces a giant local enhancement of spin-orbit coupling due to sp(3) hybridization which depends strongly on the local lattice distortion. Guided by the reduced symmetry and the local structure of the induced dipole moments, we use group ...

We have employed the Douglas-Kroll-Hess approximation to derive the perturbative Hamiltonians involved in the calculation of NMR spin-spin couplings in molecules containing heavy elements. We have applied this two-component quasirelativistic approach using finite perturbation theory in combination with a generalized Kohn-Sham code that includes the spin-orbit interaction self-consistently and w...