Industrial Fischer-Tropsch processes involve the synthesis of hydrocarbons usually on metal surface catalysts. On the other hand, very few homogeneous catalysts are known to perform a Fischer-Tropsch style of reaction. In recent work, we established the catalytic properties of a diruthenium-platinum carbene complex, [(CpRu)₂(μ²-H) (μ²-NHCH₃)(μ³-C)PtCH₃(P(CH₃)₃)₂](CO)n⁺ with n=0, 2 and Cp=η⁵-C₅(...

Water increases Fischer-Tropsch synthesis (FTS) rates on Ru through H-shuttling processes. Chemisorbed hydrogen (H*) transfers its electron to the metal and protonates the O-atom of CO* to form COH*, which subsequently hydrogenates to *HCOH* in the kinetically relevant step. H2 O also increases the chain length of FTS products by mediating the H-transfer steps during reactions of alkyl groups w...

Kunert and Martin (2000) determined optimal and efficient block designs in a model for field trials with interference effects, for block sizes up to 4. In this paper we use Kushner’s method (Kushner, 1997) of finding optimal approximate designs to extend the work of Kunert and Martin (2000) to optimal designs with five or more plots per block. We give an overall upper bound at,b,k for the trace...

an alumina supported co/ni catalyst was prepared by sol-gel procedure to study the catalytic behavior during fischer-tropsch synthesis in a fixed-bed reactor. the effect of co conversion (10-50%) on hydrocarbon product distribution (ch4, c5+ and c2-c4 olefin selectivities) was studied. selectivity for ch4 decreased, while those of c5+ and olefin selectivities increased with increasing co conver...

In this work the distillation column sequencing problem is addressed through the Generalized Modular Framework, based on formal superstructure optimization techniques. The proposed method overcomes structural complexities through the use of systematically composed structural models incorporating all the feasible sequencing alternatives. The generated sequences are evaluated with respect to thei...

accelerated deactivation of co/al2o3 catalysts in fischer-tropsch synthesis and the effect of re and ru as the catalytic promoters are reported. 15wt% co/al2o3 catalyst and 1wt% ru and 1.4wt% re  promoted cobalt catalysts have been formulated and extensively characterized. the deactivation of the unpromoted cobalt catalyst and those promoted with re and ru were studied by accelerated method at ...

Deactivation of cobalt and nickel catalysts in Fischer-Tropsch synthesis and methanation JAVIER BARRIENTOS Akademisk avhandling som med tillstånd av KTH i Stockholm framlägges till offentlig granskning för avläggande av teknologie doktorsexamen fredagen den 23 september kl. " True wisdom comes to each of us when we realize how little we understand about life, ourselves, and the world around us....

A series of small and well defined cobalt nanoparticles were synthesized by the chemical reduction of cobalt salts in water using NaBH4 as a reducing agent and using various polymeric stabilizers. The obtained nanocatalysts of similar mean diameters (ca. 2.6 nm) were fully characterized and tested in the aqueous phase Fischer-Tropsch Synthesis (AFTS). Interestingly, the nature and structure of ...