Submitted for the MAR09 Meeting of The American Physical Society A Microscopic Model for the Reinforcement and the Non Linear Behaviour of Filled Elastomers and Thermoplastic Elastomers (Payne and Mullins Effects) DIDIER LONG, CNRS/Rhodia, SAMY MERABIA1, CNRS/Univ. Paris Sud, PAUL SOTTA, CNRS/Rhodia — We present a model regarding reinforcement properties of nanostructured polymers. Then, we sho...

We consider the impact of the elastomer network on the nematic structure and fluctuations in isotropic-genesis nematic elastomers, via a phenomenological model that underscores the role of network compliance. The model contains a network-mediated nonlocal interaction as well as a new kind of random field that reflects the memory of the nematic order present at network formation and also encodes...

Numerous models of industrial processes such as diffusion in glassy polymers or solidification phenomena, lead to general one-phase free boundary value problems with phase onset. In this paper we develop a framework viable to prove global existence and stability of planar solutions to one such multidimensional model whose application is in controlled-release pharmaceuticals. We utilize a bounda...

We show that the relaxational dynamics as exhibited in the enthalpy relaxation of the density wave compounds at very low temperatures (T<lK) is very similar to that one occuring in disordered systems such as glassy polymers or spin glasses. We discuss these similarities, as well as some pecularities, in the frame of secondary relaxational processes as genuine features of glass formers below the...

Many practically relevant polymers undergoing desorption change from the rubbery (saturated) to the glassy (nearly dry) state. The dynamics of such systems cannot be described by the simple Fickian diffusion equation due to viscoelastic effects. The mathematical model solved numerically is a set of two coupled PDEs for concentration and stress. Asymptotic solutions are presented for a moving bo...

Reiter has recently reported a situation in which the dewetting of quasi-solid films is linked to plastic deformation--rather than viscous flow--resulting from capillary forces. Herein we propose that, in thin films of some glassy polymers--especially poly(methyl methacrylate) (PMMA)--prepared by spin-casting from solvent, structural relaxation might impart sufficient stress to cause plastic de...

In a recent letter, Govaert et al. examined the relationship between strain hardening modulus Gr and flow stress σflow for five different glassy polymers. In each case, results forGr at different strain rates or different temperatures are linearly related to the flow stress. They noted that this linear relation is different than a simple proportionality between Gr and σflow, which they claimed ...

A molecularly imprinted polymers based electrochemical sensor was fabricated by electropolymerizing pyrrole on a Fe3O4 nanoparticle modified glassy carbon electrode. The sensor showed highly catalytic ability for the oxidation of 2,4-dichlorophenol (2,4-DCP). Square wave voltammetry was used for the determination of 2,4-DCP. The oxidation peak currents were proportional to the concentrations of...