The Helmholtz free energy F of the interacting 2-D electron fluid is calculated nonperturbatively using a mapping of the quantum fluid to a classical Coulomb fluid [Phys. Rev. Letters, 87, 206 (2002)]. For density parameters rs such that ∼ 25 < rs, the fluid is unpolarized at all temperatures t = T/EF , where EF is the Fermi energy. For lower densities, the system becomes fully spin polarized f...

The lattice cluster theory (LCT) for the thermodynamics of polymer systems has recently been reformulated to treat strongly interacting self-assembling polymers composed of fully flexible linear telechelic chains [J. Dudowicz and K. F. Freed, J. Chem. Phys. 136, 064902 (2012)]. Here, we further extend the LCT for linear telechelic polymer melts to include a description of chain semiflexibility,...

Electron energy probability functions EEPFs are measured across the radius 0 r 6.85 cm of a low pressure 0.3 mTorr helicon plasma source terminated by a current-free double layer. The source field of about 130 G is generated using a Helmholtz coil pair and the radio frequency rf power is maintained at 250 W. All EEPFs exhibit a distribution with a temperature Te bulk out to a break energy break...

Hong Qian Department of Applied Mathematics, University of Washington, Box 352420, Seattle, WA 98195, USA Abstract The consistency across scales of a recently developed mathematical thermodynamic structure, between a continuous stochastic nonlinear dynamical system (diffusion process with Langevin or Fokker-Planck equations) and its emergent discrete, inter-attractoral Markov jump process, is i...

Describing kinetic processes within a perturbation theory approach such as Fermi's golden rule requires an understanding of the initial and final states of the system. A number of different methods have been proposed for obtaining these diabatic-like states, but a robust criterion for evaluating their accuracy has not been established. Here, we approach the problem of determining the most appro...

We propose a density-functional theory (DFT) describing inhomogeneous polymer-carbon dioxide mixtures based on a perturbed-chain statistical associating fluid theory equation of state (PC-SAFT EOS). The weight density functions from fundamental measure theory are used to extend the bulk excess Helmholtz free energy to the inhomogeneous case. The additional long-range dispersion contributions ar...

In acoustic energy, harvesting energy is captured from external noise sources, controlled and stored for various applications. Despite the prevalence of acoustic energy a major challenge of energy harvesting is the low power density. Acoustic Energy Harvester consists of a resonator, an acoustic transducer and a storage device. When acoustic resonator is excited by an incident wave at its reson...

We study phase separation in ionic solutions confined by solid objects carrying surface charges. Within the framework of Density Functional Theory, the Helmholtz free energy of the ionic solution is minimized under canonical constraints on the ionic densities fixing their mean value while ensuring global electroneutrality. The free energy splits into a bulk and an electrostatic contribution. Th...

Recent experimental studies [Z. Wu, B. Zhou, Z.B. Hu, Phys. Rev. Lett. 90 (2003) 048304] on an uncharged aqueous poly-N-isopropylacrylamide (PNIPAM) dispersion have shown that this microgel system is sensitive to temperature. This system was also experimentally found to be modeled quite well by microgel particles interacting via a hard-sphere repulsive plus an inverse power (temperature-depende...

This article explores the notion that Freudian constructs may have neurobiological substrates. Specifically, we propose that Freud's descriptions of the primary and secondary processes are consistent with self-organized activity in hierarchical cortical systems and that his descriptions of the ego are consistent with the functions of the default-mode and its reciprocal exchanges with subordinat...