Cyclodextrin poly-functionalization has fueled progress in their use multiple applications such as enzyme mimicry, but also the polymer sciences, luminescence, sensors or for biomedical applications. However, regioselective access to a given pattern of functions on β-cyclodextrin is still very limited. We uncover new orienting group, thioacetate, that expands toolbox available cyclodextrin poly...

Fe2V4O13 is prepared and characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), UV-diffuse reflectance spectroscopy (UV-DRS), high resolution scanning electron microscopy (HR-SEM) using energy dispersive X-ray spectroscopy (EDX) analysis. The hetero-Fenton catalyst can be used to mineralize Methyl Orange (MO) under UV-A light. The mineralization rate is influenced by hydr...

A family of furoquinolines were efficiently obtained through a tandem acetalization/cycloisomerization process catalyzed by (5 mol%) silver imidazolate polymer and triphenylphosphine, and diversity was brought by the use of 7 different alcohol groups. From these furoquinolines, 3 examples of reduced derivatives could be obtained (d.r. up to 94 : 6), 10 different spiroketal derivatives by hetero...

A short and robust approach for the synthesis of 2-(hetero)aryl substituted thieno[2,3-b]indoles from easily available 1-alkylisatins and acetylated (hetero)arenes has been advanced. The two-step procedure includes the "aldol-crotonic" type of condensation of the starting materials, followed by treatment of the intermediate 3-(2-oxo-2-(hetero)arylethylidene)indolin-2-ones with Lawesson's reagen...

Based on the overlap integral of electromagnetic fields in neighboring cores, a calculating method is proposed for obtaining the coupling coefficient between two adjacent trench-assisted non-identical cores. And a kind of heterogeneous trench-assisted multi-core fiber (Hetero-TA-MCF) with 12 cores is proposed to achieve large effective area (A(eff)) and high density of cores. As bending radius ...

A convolutional neural network is trained in auto/hetero-associative mode for reconstructing RGB components from a randomly mosaicked color image. The was shown to perform equally well when images are sampled periodically or with different random mosaic. Therefore, this model able generalize on every type of filter array. We attribute property universal demosaicking the learning statistical str...

An efficient Pd-catalyzed one-pot desulfinative cross-coupling to access medicinally relevant di(hetero)arylmethanes is reported. The method reductant-free, and involves a sulfinate transfer reagent Pd-catalyst mediating the union of two electrophilic coupling partners; (hetero)aryl halide benzyl halide. We establish for first time that sulfinates, generated in situ, undergo with halides genera...

Hydroxypyridone and pyridopurine homo- and hetero-base pairs have been investigated in the context of duplex GNA (glycol nucleic acid). Phosphoramidites for automated GNA solid phase synthesis were synthesized economically in a few steps starting from commercially available enantiopure glycidol. Similar to their behavior in DNA, the hydroxypyridone and pyridopurine homo-base pairs display a met...

Sequential embedding of metal complexes 4?-(pyridin-4-yl)-2,2?:6?,2??-terpyridine to a surface-enhanced supports pre-functionalized with templating layer results in hetero-bimetallic (Os–Fe, Co–Fe) and hetero-trimetallic (Co–Os–Fe) monolayer materials.