Indium-promoted coupling reactions between propargyl aldehydes (1) and alpha-chloropropargylphenyl sulfide are reported. Although water has been shown to accelerate indium metal promoted reactions, the reverse pattern was observed in this series. Use of N-methylformamide (NMF), which has not previously been a solvent known for use in indium-promoted reactions, afforded an acceleration of these ...

OBJECTIVES The aim of this study was to clarify the chronic toxicological effects of indium-tin oxide (ITO) and indium oxide (In(2)O(3)) on laboratory animals. METHODS Male Syrian golden hamsters were intratracheally administered 3 mg/kg or 6 mg/kg of ITO particles, or 2.7 mg/kg or 5.4 mg/kg of In(2)O(3) particles, containing 2.2 mg/kg or 4.5 mg/kg of indium, twice a week, for 8 wk. Control h...

THE MINING REPORT Luisa Moreno, managing partner and analyst with Toronto-based Tahuti Global, says there are many things investors must pay attention to when it comes to critical metals projects, but nothing should trump metallurgy. That's because no two deposits are precisely the same, and having a clear understanding of how to economically recover those metals and get them into end-users' ha...

A series of (±)- and (R,R)-tridentate diamino, ortho/para disubstituted phenolate proligands H(NNO(R)) with various phenolate substituents was synthesized and used to prepare indium dichloride complexes (NNO(R))InCl2via salt metathesis of the deprotonated ligands with indium trichloride. These complexes are dinuclear in the solid state, in contrast to previously reported complexes with t-butyl ...

The correlation between defect structure, metal segregation, and electrical resistivity of indium-tin-oxide nanopowder upon treatment in reducing atmosphere was investigated. Morphology and defect structure have been investigated by in situ synchrotron x-ray diffraction and transmission electron microscopy, while traces of metallic indium have been detected by susceptibility measurements utiliz...

An in situ investigation of thermal decomposition reactions of trimethylindium (TMIn) in a vertical, upflow chemical vapor deposition reactor has been carried out using Raman spectroscopy. Monomethylindium (MMIn) and atomic indium were detected along with the precursor TMIn using N2 as the carrier gas. Atomic indium was identified by the peak at 2215 cm, which is equal to the difference between...

We have used the indium/copper surface alloy to study the dynamics of surface vacancies on the Cu(001) surface. Individual indium atoms that are embedded within the first layer of the crystal, are used as probes to detect the rapid diffusion of surface vacancies. STM measurements show that these indium atoms make multi-latticespacing jumps separated by long time intervals. Temperature dependent...

A challenge in the development of nanometer-scale devices, which are envisioned to impact human life in the near future, is the development of economical techniques for the fabrication of their building blocks. Owing to their unique and exquisite characteristics, nanowires are ideal building blocks for functional nanometer-scale electronics, photonic structures, and nanosurgery devices. Here, w...

regioselective synthesis of highly functionalized pyranopyrazoles was achieved in excellent yield from phenyl pyrazolone, substituted aromatic aldehyde with nitroketene-n,s-acetal in the presence of indium trichloride as a versatile catalyst under reflux condition in ethanol-water mixture. all reactions preceeded within a short period of time with excellent purity. all of the synthesized compou...