Recently there has been considerable interest in the utilization of covalent-organic frameworks (COFs) as ion-exchange membranes. While rapid ion conduction is experimentally observed COF membranes, underlying mechanism remains elusive. Herein, we report a molecular simulation study on chloride (Cl−) four membranes functionalized with quaternary ammonium groups (QA-2, QA-4, QA-6 and QA-EO) diff...