Oxovanadium(IV), manganese(II) and copper(II) complexes of a Schiff base ligand derived from 2,4-dihydroxyacetophenone and 1,2-diaminocyclohexane have been encapsulated in the nanocavity of zeolite-Y by flexible ligand method and characterized by metal analysis, IR spectroscopic studies and X-ray diffraction patterns. The encapsulated complexes abbreviated here as CuL-Y, MnL-Y and VOL-Y catalyz...

we present detailed theoretical studies of the h-bonded complexes formed from interaction between 5-fluorouracil and various six-membered cyclic nitrosamine compounds. in this study, an investigation on intermolecular interactions in x-nu (x = ch2, sih2,bh, alh, nh, ph, o and s) complexes is carried out using density functional theory. the calculations are conducted on b3lyp/6-311++‏‏g** level ...

new two nano- sized schiff base complexes [m(l)], where l= 2, 2'-((1e, 1e')-(1, 2 phenylen bis (azanylylidene)) bis (methanylylidene)) bis (4-bromo phenolato) and m=cu or zn, (a, b complexes) were synthesized by ultrasonic irradiation. these complexes were characterized by elemental analysis, molar conductivity, ft-ir, fluorescence emission, 1h nmr, field emission scanning electron sp...

In this research at the first complexes were optimized. NBO calculations and NMR for the complexes were carried out at the B3LYP/6-31G*quantum chemistry level. Different parameters such as energy levels, the amount of Chemical Shift in different atoms, the amount of HOMO/LUMO, chemical potential (µ ), chemical hardness (η), Formazan dyes have become important reactive dyes for cotton. Formazan ...

N-propylsalicylidene based on silica as ion exchanger (IE) was used for the separation by complexation of Mn2+, Co2+, Ni2+, Cu2+, Hg2+, Cr3+, Fe3+, and UO22+ from their parent solutions. IE and its metal complexes are characterized by elemental analysis, electronic and infrared spectra, in addition to thermal analysis in atmospheric pressure. The mode of chelation and the proposed geometric str...

This paper is concerned with the derivation and properties of differential complexes arising from a variety problems in equations, applications continuum mechanics, relativity, other fields. We present systematic procedure which, starting well-understood such as de Rham complex, derives new deduces old. relate cohomology output complex to that input show has closed ranges, and, consequently, sa...

Let $mathcal{X}$ be a class of $R$-modules‎. ‎In this paper‎, ‎we investigate ;$mathcal{X}$-injective (projective) and DG-$mathcal{X}$-injective (projective) complexes which are generalizations of injective (projective) and DG-injecti‎‎ve (projective) complexes‎. ‎We prove that some known results can be extended to the class of ;$mathcal{X}$-injective (projective) and DG-$mathcal{X}$-injective ...