The three-coordinated homoleptic Cu(I) complex with 2,6-dimethylphenyl isocyanide in the coordination sphere was easily synthesized and isolated as tetrafluoroborate salt. structure of compound determined by single-crystal X-ray diffraction. is highly stable, active selective toward copper-catalyzed azide-alkyne cycloaddition, working neat conditions absence bases at room temperature. Substrate...

Sulfur‐centered radicals have a key role in plethora of synthetic organic transformations, whose scope has been further expanded thanks to the possibility generate such species under visible light photocatalytic conditions. The current literature overview focuses on those transformations involving isocyanides and sulfur‐centered with aim highlight chemical space accessible, both terms complexit...

The synthesis and structural diversification of N-heterocycles systems have attracted much attention because their potential applications. Three 6-aryl-3-methyl-1-phenyl-1H-pyrazolo[3,4-b]pyridine-5-carbaldehyde 4 derivatives, in reaction with acetophenones 5, via conventional Claisen–Schmidt condensation reactions, generated the respective enones. enones were used as electron-deficient olefins...

Abstract An efficient and straightforward approach has been established for the preparation of a new class depsipeptide structures via isocyanide-based consecutive Bargellini–Passerini multicomponent reactions. 3-Carboxamido-isobutyric acids bearing an amide bond were obtained Bargellini reaction from isocyanides, acetone, chloroform in presence sodium hydroxide. Next, Passerini multicomponent-...

Treatment of the [AuCl(tetrahydrothiophene)] complex with 4-chloro-2-iodo-1-isocyanobenzene furnished gold(I) compound [AuCl(CNC6H3-4-Cl-2-I)] (1). In crystal structure 1, linear C–Au–Cl group is subject to solid-state head-to-tail pairing, which determined by aurophilic Au⋯Au and rare π-holeCN⋯Cl interactions. These two types structure-determining interactions are complementary each other, sys...