An electron density map of the large ribosomal subunit from Bacillus stearothermophilus was obtained at 26 A resolution by single isomorphous replacement (SIR) from a derivative formed by specific quantitative labeling with a dense undecagold cluster. For derivatization, a monofunctional reagent of this cluster was bound to a sulfhydryl group of a purified ribosomal protein, which was in turn r...

The structure of the catalytic core of the endoglucanase V (EGV) from Humicola insolens has been determined by the method of multiple isomorphous replacement at 1.5 A resolution. The final model, refined with X-PLOR and PROLSQ, has a crystallographic R factor of 0.163 (R(free) = 0.240) with deviations from stereochemical target values of 0.012 A and 0.037 degrees for bonds and angles, respectiv...

The present study set out to investigate the effect of teaching substitution as a kind of grammatical cohesion on the true identification of confusing substitution elements with cohesive or non-cohesive roles in different contexts and also the production of modal, reporting and conditional contexts through clausal substitution acquaintance. To this end, the following procedures were taken. Firs...

It is shown that the antisymmetry of the sphalerite structure is isomorphous to the coloured diamond group Fd'3'm if sites associated with positive and negative charge are regarded as being equivalent except for colour. This methodology enables the multiplicity and polarity of external crystal surfaces to be deduced readily. In addition this analysis is shown to be very useful for the analysis ...

The title compound, C26H25BrN2, is isomorphous with the chloro derivative [2-(4-chloro-phen-yl)-1-pentyl-4,5-diphenyl-1H-imidazole; Mohamed et al. (2013 ▶). Acta Cryst. E69, o846-o847]. The two phenyl rings and the 4-bromo-phenyl ring are oriented at dihedral angles of 30.1 (2), 64.3 (3) and 42.0 (2)°, respectively, with respect to the imidazole ring. In the crystal, mol-ecules stack in columns...

The crystal structure of the intermediate phases in the binary systems of titanium with iron, cobalt, and nickel has been studied and the results compared with those previously published. The phases of the Ti2X type are face-centered cubic with % atoms per cell, and the TiX phases are body-centered cubic. TiFe, and Tic02 are hexagonal but not isomorphous. The nickel-rich phase has the compositi...

The title compounds, C18H22Cl2N2O2 and C20H28N2O2, respectively, are isomorphous. The molecules lie at general positions in the unit cell. In each structure, chemically equivalent but crystallographically inequivalent amine N atoms exhibit different degrees of pyramidalization. The structures exhibit weak NÐH N hydrogen bonding, which is in ̄uenced by the differences in hybridization around the ...

The title compound, [PdCl(2)(C(8)H(11)O(2)P)(2)], has a comparable structure to those of related palladium dichloride complexes containing trimethyl phosphinite and methyl diphenyl phosphinite. The Pd atom is located on a crystallographic twofold rotation axis: thus, there is just one half-mol-ecule in the asymmetric unit. The structure is isomorphous with the platinum analogue cis-[PtCl(2){P(O...

The photocatalytic degradation process and absorption kinetics of the aqueous solution Cibacron Brilliant Yellow 3G-P dye (Y) were investigated under UV-Vis light. Pure barium titanate BaTiO3 (BT) cobalt ion-substituted Ba1−xCoxTiO3 (x = 0, …, 1) nano-compound powders (BCT) synthesized using sol–gel method colloidal destabilization, utilized as photocatalysts. powder X-ray diffraction (PXRD) cr...