The statistics of steps and dwell times in reversible molecular motors differ from those of cycle completion in enzyme kinetics. The reason is that a step is only one of several transitions in the mechanochemical cycle. As a result, theoretical results for cycle completion in enzyme kinetics do not apply to stepping data. To allow correct parameter estimation, and to guide data analysis and exp...

Isothermal melt crystallization kinetics of PVDF was investigated by differential scanning calorimetry. Thin PVDF film has been fabricated by the solvent casting technique using dimethylformamide (DMF). Then, the samples were melted and subsequently crystallized in the range of the crystallization temperature (Tc) between 138 and 145 °C. The crystallization kinetics was derived from Avrami equa...

Precipitation behaviour of wrought Al-6Mg alloys with ternary scandium and quaternary zirconium and titanium has been studied. Hardness measurements and resistivity studies are employed to assess the precipitation behaviour of scandium doped Al-6Mg alloy without or with quaternary additions of zirconium and titanium. Further, the kinetics of precipitations are studied by differential scanning c...

In this research, Graphene Oxide- Gold nanoparticles (AuNP/GO) were easily fabricated by a redox reaction between GO and chloroauric acid without using any additional reductant and then used to stabilize Pickering emulsions. (AuNP/GO) was investigated by FT-IR spectroscopy. The changes of parameters such as contact time, pH, Amoxicillin initial concentration and temperature were tested and inve...

Removal of fluoride ions was investigated using a new adsorbent of yttrium alginate biocomposite (YALG). Effect of various parameters such as pH, contact time, initial concentration of fluoride ions and temperature on the sorption capacity of adsorbent was studied. Performing a mathematical assessment of fluoride sorption, isotherm and kinetics models including Freundlich & Langmuir isotherms a...

abstractbackground and objectives:the phosphorus is second limiting nutrient in soil for crop production after nitrogen. mobility and availability of phosphorus (p) in soils is affected by phosphorus desorption characteristics. information about the effect of organic matter on kinetics and thermodynamics of p desorption in calcareous soils of east azerbaijan province is limited. the objective o...

A 'first-passage-time' analysis is applied to enzyme kinetics. It is shown that the residence times determined in this way are directly related to the steady-state parameters and are particularly useful in analysis of isotopic exchange. A simple linear means is used for the calculation of these residence times that makes this method easily applicable to the numerical evaluation of complex model...

A novel method of estimating enzyme kinetic parameters is presented using the Lambert omega function coupled with nonlinear regression. Explicit expressions for the substrate and product concentrations in the integrated Michaelis-Menten equation were obtained using the omega function which simplified kinetic parameter estimation as root-solving and numerical integration of the Michaelis-Menten ...

Many common kinetic model reduction approaches are explicitly based on inherent multiple time scales and often assume and directly exploit a clear time scale separation into fast and slow reaction processes. They approximate the system dynamics with a dimension-reduced model after eliminating the fast modes by enslaving them to the slow ones. The corresponding restrictive assumption of full rel...