The importance of anharmonic effect on dissociation of molecular systems, especially clusters, has been noted. In this paper, we shall present a theoretical approach that can carry out the first principle calculations of anharmonic canonical and microcanonical rate constants of unimolecular reactions within the framework of transition state theory. In the canonical case, it is essential to calc...

The behaviour of the spectral edges (embedded eigenvalues and resonances) is discussed at the two ends of the continuous spectrum of non-local discrete Schrödinger operators with a δ-potential. These operators arise by replacing the discrete Laplacian by a strictly increasing C1-function of the discrete Laplacian. The dependence of the results on this function and the lattice dimension are expl...

The Exterior-Interior duality expresses a deep connection between the Laplace spectrum in bounded and connected domains in R, and the scattering matrices in the exterior of the domains. Here, this link is extended to the study of the spectrum of the discrete Laplacian on finite graphs. For this purpose, two methods are devised for associating scattering matrices to the graphs. The Exterior -Int...

In this study, Laplace transformation, which is very important for solutions to initial value problems, examined. To solve the problem of a discrete‐time equation, implements conversion method. Here, transformation used obtain an approach random difference equations formed by randomizing components deterministic equations. For behavior linear under effects, uniform, geometric, binomial, Poisson...