A redox amination strategy was developed for the synthesis of N-aryl-1-aminoindoles by N-N bond formation. Reaction of nitrosobenzenes with readily available indolines using Brønsted acid catalysis allows N-N bond formation under mild conditions. This method exploits the inherent reducing power of indoline to synthesize biologically relevant molecular architectures via redox amination. A one-po...

involving additional fields Φ̂I(z1)Φ̂I(z2) · · ·. Note that in eq. (3) the fields are in the interaction rather than Heisenberg picture, so they evolve with time as free fields according to the free Hamiltonian Ĥ0. Likewise, |0〉 is the free theory’s vacuum, i.e. the ground state of the free Hamiltonian Ĥ0 rather than the full Hamiltonian Ĥ. To work out the relation between (1) and (3), we start b...

A microfluidic device capable of exploiting the permeability of small molecules through polydimethylsiloxane (PDMS) has been fabricated in order to control the contents of microdroplets stored in storage wells. We demonstrate that protein precipitation and crystallization can be triggered by delivery of ethanol from a reservoir channel, thus controlling the protein solubility in microdroplets. ...

Traditionally, multiple IC chips are needed to build transmitters (Tx) used in wireless communications. The difficulty with a full Tx integration is that each Tx building block uses different technology. A power-detection circuit will exploit the Schottky diode, while the modulator IC is integrated with BiCMOS or SiGe. Likewise, the digital control loop is implemented in CMOS. Now that directco...

We numerically examine the extension of tethered worm-like chains in shear flow, obtaining agreement with scaling arguments that invoke thermal fluctuations and the specific nonlinearity of the WLC force law. The transient tension distribution is obtained and likewise found to reflect nonlinearity and finite extensibility. Cyclic dynamics of the chain free end are observed. Numerical simulation...

The title complex, [CdCl(2)(C(9)H(12)N(4))](n), is characterized by the formation of a zigzag chain structure parallel to [001]. In the chain, the Cd(2+) cation is coordinated by four bridging Cl(-) ligands in equatorial positions and two N atoms from symmetry-related and likewise bridging 1,3-bis-(imidazol-1-yl)propane ligands in axial positions, forming a distorted CdCl(4)N(2) octa-hedron.

The integration of a rule representation in ontology languages enhances the developer’s abilities in the expression of knowledge. Likewise the integration creates new challenges for the design process of these knowledge bases. Thus, evaluation approaches have to cope with the merged methods. We introduce extensions to existing verification techniques to support the implementation of ontologies ...

Group assortative biases are stronger in regions where pathogen stress has been historically prevalent. Pushing the logic of this approach, extensions should include investigations of how cultural norms related to prosociality and relational striving may also covary with regional pathogen stress. Likewise, the pan-specific observation that diseased animals show decreased motor activity to facil...

2. The above conclusions are not supported by research performed on older athletes. When healthy regular exercisers 55-70 years old are compared with young adults of similar aerobic fitness, acclimation state, body size, and body composition, both groups respond with similar rates of heat storage and similar body core temperatures during exercise in the heat. Likewise, older athletes and young ...

This paper attempts to introduce the GENSEC security subsystem and client credentials interfaces to interested bystanders and developers on the Samba4 project. GENSEC attempts to abstract details about user authentication into a single place, providing a simple API to the rest of Samba, while remaining compatible with Microsoft’s implementations of the same security protocols. Likewise the clie...