A downfield shift of proton signals up to 9 ppm is induced in the 1H NMR spectra of juvenile hormone I (methyl 3,11-dimethyl-10,11-cis-epoxy-7-ethyl-2-trans, 6-trans-tridecadienoate) and III (methyl 10,11-epoxy-2-trans, 6-trans-farnesoate) by the lanthanide complex Eu(fod)3. A plot of induced shift vs the ratio of [LSR]/[substrate] shows a good linear correlation for the range 0.3--1.0 mole rat...

the usage of turbochargers in diesel engines has led to the downsizing of the motors as well as usage of the waste gates in turbochargers. any dimensional reduction in turbochargers and appurtenant leads to an enhancement on the performance of internal combustion engines and in environmental problems in terms of aerodynamic, thermodynamic and mechanical specifications for both engines and turbo...

We have observed an object having strong Balmer absorption lines and blue continuum. The inference about the nuclear stellar population drawn from the line ratios is basically coincident with that drawn from the continuum color, both indicating the dominant fraction of early A type population in the nucleus. This might be expected only if there has been a very massive starburst, burst strength ...

a proton nmr method for the drtermination of salvation numbers of alkaline earth cations with hexamethyl phosphoramide (hmpa) in nitromethane (nm) as diluents is described. the method is based on monitoring the resonance frequency of hmpa protons as a function of hmpa / metal ion molar ratio at constant metalion concentration. the average salvation number of cations,  , at any hmpa / metal ion ...

Besides its decorative handicraft antiques and other conventional uses, the importance of bamboo crop has been increased due to its use in textiles as a vegetable fibre. The absorbent nature of bamboo fibre has lead to its various applications in textiles. The focus of present research is to optimize the quality of bamboo/cotton blends. Therefore, present study investigates the influence of bam...

In this study, the concrete-steel bond strength of concrete filled cylindrical steel tubes has been experimentally investigated. 22 short, high strength and normal concrete filled circular steel tubes were tested. Push-out test was carried out as the common method to evaluate the bond carrying capacity. Four different concrete mixes were used in preparing the specimens. The steel tubes were w...

Deep beams are commonly used in tall buildings, offshore structures, and foundations. According to many codes and standards, strut-and-tie model (STM) is recommended as a rational approach for deep beam analyses. This research focuses on the STM recommended by ACI 318-11 and AASHTO LRFD and uses experimental results to modify the strut effectiveness factor in STM for reinforced concrete (RC) de...

A proton NMR method for the drtermination of salvation numbers of alkaline earth cations with hexamethyl phosphoramide (HMPA) in nitromethane (NM) as diluents is described. The method is based on monitoring the resonance frequency of HMPA protons as a function of HMPA / metal ion molar ratio at constant metalion concentration. The average salvation number of cations,  , at any HMPA / metal ...

Two fractions of sarcoplasmic reticulum, one light (LSR) and one heavy (HSR), were isolated from gracilis muscle of control and malignant hyperthermia (MH)-susceptible pigs. Part of the gracilis muscle biopsy was used to compare the contracture sensitivity of the muscle to the calcium-releasing effects of caffeine on isolated SR membranes. Gracilis muscle of MH pigs was more sensitive to the co...