In order to study the Cu(II) ion selective electrode, an optimized membrane was prepared by mixing of 30 mg of PVC powdered, 5 mg of considered ionophore, 60 mg of plasticizer and 5 mg of additive. The sensor showed a near Nernstian response for Cu(II) ions over a concentration range from 1.0×0-6 –1.0×0-2 M with a slope of 28.90.5 mV per concentration decade with a working pH range of 3.5-6.3. ...

The potassium-selective glass membranes like KAS,,_, and NAS,,_, are approx. IO times more sensitive to K+ than to Na +lp3. Since the concentration ratio of Na+/K+ in blood serum is around 35-40 and since there is at best a K+ over Naf selectivity in glass electrodes of IO, a separate measurement of the Na+ concentration is needed to correct the reading of the K+ sensor 4. Because of the depend...

This paper deals with the development of a liquid measuring instrumentation using the popular tetrapolar electrode configuration. The system consists of four-electrode ring shape using Cromium metal plate and a small measurement. The developed instrument is calibrated with the help of prepared saline solution prepared in lab. A liquid of known parameter is placed inside the measurement cell and...

A novel fiber-optic electrochemiluninescence sensor has been developed. It can be conveniently applied by placing into the sample solution in a manner similar to a conventional ion selective electrode, without requiring liquid luminous reagent and a flowing system. The sensor is consisted of an independent probe and a case for exclusion the ambient light, allowing the sample solution to pass th...

Aqueous electrolytes are very effective for supercapacitor applications but their narrow electrochemical potential window (∼1 V) and associated limited energy currently limits use. Here, we demonstrate a new strategy to enlarge the by designing an artificial interface ( ai ). An was achieved via mixture of siloxanes doped with ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfony...

Abstract Water management is a critical challenge in low temperature (LT) Proton Exchange Membrane Fuel Cells (PEM FC); condensed liquid appears mainly at the cathode side, where water from reduction reaction generated. Differences concentration may result transfer of to anode side across membrane electrode assembly (MEA). Excessive can negatively affect fuel cell performance, causing efficienc...

An indium tin oxide glass electrode coated with poly(3,4-ethylenedioxythiophene), PEDOT, PEDOT-ITOE, was proposed as an electrode workable as both a reference electrode and a counter one, a reference/counter electrode, in an organic phase and applied to a thin-layer cell of a two-electrode system for voltammetry at the liquid | liquid interface. By oxidizing the PEDOT film by 50% and doping a s...

A PVC-based membrane electrode for lead ions based on hexathia-18-crown-6-tetraone as membrane carrier was prepared. The influence of membrane composition, pH of test solution and foreign ions on the electrode performance were investigated. The electrode showed a Nernstian response over a lead concentration range from 1.0 x 10(-6) to 8.0 x 10(-3) M at 25 degrees C, and was found to be very sele...