Carbon film disk electrodes with Nafion coatings have been characterized by electrochemical impedance spectroscopy (EIS) with a view to a better understanding of their advantages and limitations in electroanalysis, particularly in anodic stripping voltammetry of metal ions. After initial examination by cyclic voltammetry, spectra were recorded over the full potential range in acetate buffer sol...

Organic-inorganic metal halide perovskite solar cells were fabricated by laminating films of a carbon nanotube (CNT) network onto a CH3NH3PbI3 substrate as a hole collector, bypassing the energy-consuming vacuum process of metal deposition. In the absence of an organic hole-transporting material and metal contact, CH3NH3PbI3 and CNTs formed a solar cell with an efficiency of up to 6.87%. The CH...

This letter describes a replacement (damascene) metal gate NMOSFET with TaSiN and PVD TaN as stacked gate electrode. The goal is to perform the “gate electrode engineering” in order to change the work function and the threshold voltage of the transistor. An annealing at 400°C after the metal gate is formed significantly improves the transistor performance. The subthreshold slope is measured to ...

A “capacitive-piezo” transducer that combines the strengths of capacitive and piezoelectric mechanisms to achieve an impedance and Q simultaneously lower and higher, respectively, than otherwise attainable by either mechanism separately, has allowed demonstration of a 1.2-GHz contour-mode AlN ring resonator with a motional resistance of 889 Ω and Q=3,073 higher than so far measured for any othe...

A mathematical model f or the electrochemical impedance spectroscopy of a metal-hydride electrode was developed. The model was used to study the effect of various parameters on predicted kinetic behavior. The simulations obtained using the model show that the first arc appearing in the higher frequency range is due to a charge-transfer reaction, the second arc in the middle frequency range repr...

A silver ion-selective electrode was prepared with a polymeric membrane incorporating 2,6-bis-methylsulfanyl-[1,3,5]thiadiazine-4-thione as an ionophore, tri-n-butylphosphate (TBP) as a plasticizer and sodium tetraphenylborate (NaTPB) as an additive. The electrode exhibited a near-Nernstian response of 52 mV/decade over a wide linear concentration range of 1.0 x 10(-5) - 1.0 x 10(-1) M with a l...

Objectives • Elucidate rates and mechanisms of the degradation of polymer electrolyte fuel cell (PEFC) platinum electrode performance – Effect of electrolyte, potential (holding and cycling), time, and temperature • Develop non-platinum cathode electrocatalysts for PEFCs – Transition metal carbides and nitrides – Bi-metallic systems – Metal centers attached to electron-conducting polymer backbones

This paper reports a micromachined chemical sensor intended for harsh environments such as those near hydrothermal vents at the sea floor. The sensor is intended to measure the pH, dissolved H2 and H2S, and temperature. The device is 12 mm in diameter and 6 mm in effective length, including packaging. A YSZ|HgO|Hg solid electrode is used as a common electrode for measurement of the three chemic...