The 1,4-addition of a monofluoromethyl nucleophile to a variety of alpha,beta-unsaturated compounds has been achieved under mild conditions using either phosphines or potassium carbonate at room temperature. alpha-Substituted fluoro(phenylsulfonyl)methane easily undergoes Michael addition to alpha,beta-unsaturated ketones, esters, nitriles, sulfones, as well as propynoates at room temperature t...

Biomass from energy crops and agroindustrial wastes can be biologically converted to liquid or gaseous fuels, such as ethanol, methanol, methane and hydrogen, which was recently characterized as the fuel of the future. Hydrogen is a clean and environmentally friendly fuel, which produces water instead of greenhouse gases when combusted. It can be produced by renewable raw materials, such as org...

Pseudomorphism is known as a suitable technique for producing mesoscale pore in silica powders keeping their original morphologies. Herein, silica discs with several millimeter dimensions have been prepared using the same method. This method has been utilized through application of pseudomorphism reaction of preshaped bodies by immersion in a solution containing surfactant and swelling re...

Background The emerging cellulosic bioethanol industry will generate huge amounts of lignin-rich residues that may be converted into biogas by anaerobic digestion (AD) to increase the output of energy carriers from the biorefinery plants. The carbohydrates fraction of lignocellulosic biomass is degradable, whereas the lignin fraction is generally considered difficult to degrade during AD. The o...

BACKGROUND The use of energy crops and agricultural residues is expected to increase to fulfil the legislative demands of bio-based components in transport fuels. Ensiling methods, adapted from the feed sector, are suitable storage methods to preserve fresh crops throughout the year for, for example, biogas production. Various preservation methods, namely ensiling with and without acid addition...

Co-digestion of cattle slurry and maize has been shown to have benefits for both, improving the biogas yield of the slurry and stability of digestion of the maize. The effect of increasing the total loading rate from 3 to 6 g VS l(-1) day(-1) on the co-digestion of cattle slurry and maize, mixed at equal volatile solids volumes, was investigated in laboratory-scale continuously stirred digester...

To evaluate the feasibility of swine manure treatment by a proposed Dry Thermophilic Anaerobic Digestion (DT-AD) system, we evaluated the methane yield of swine manure treated using a DT-AD method with rice straw under different C/N ratios and solid retention time (SRT) and calculated the mass and energy balances when the DT-AD system is used for swine manure treatment from a model farm with 10...

To accomplish the rapid start-up and stable operation of biogas digesters, an efficient inoculum is required. To obtain such an inoculum for food waste anaerobic digestion, we domesticated dairy manure anaerobic digestion residue by adding food waste every day. After 36 days, the pH and biogas yield stabilized signifying the completion of domestication. During domestication, the microbial commu...

Enteric methane emission is the main source of greenhouse gas contribution from dairy cattle. Therefore, it essential to evaluate drivers and develop more accurate predictive models for such emissions. In this study, we built a large intercontinental experimental dataset to: (1) explain effect enteric yield (g methane/kg diet intake) feed conversion (kg intake/kg milk yield) on intensity yield)...