This paper concerns the drainage of a thin liquid lamella into a Plateau border. Many models for draining soap films assume that their gas-liquid interfaces are effectively immobile. Such models predict a phenomenon known as “marginal pinching”, in which the film tends to pinch in the margin between the lamella and the Plateau border. We analyse the opposite extreme, in which the gas-liquid int...

Core-annular flow is common in nature, representing, for example, how streams of oil, surrounded by water, move in petroleum reservoirs. Oil, typically a nonwetting fluid, tends to occupy the middle (core) part of a channel, while water forms a surrounding wall-wetting film. What is the thickness of the wetting film? A classic theory has been in existence for nearly 50 years offering a solution...

The reflection-absorption infrared (RAIRS) spectra of 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM]Tf(2)N) are presented for liquid as well as for amorphous and crystalline solid films. The liquid and amorphous films show rather similar spectra, indicating that the film structure is similar in both cases. On the other hand, these spectra differ considerably from those of...

We investigate the equilibrium of a fluid in contact with a solid boundary through a density-functional theory. Depending on the conditions, the fluid can be in one phase, gas or liquid, or two phases, while the wall induces an external field acting on the fluid particles. We first examine the case of a liquid film in contact with the wall. We construct bifurcation diagrams for the film thickne...

Understanding the phenomenon of droplet coalescence in nanoparticle suspensions is extremely important for the preparation of Pickering emulsions. A microfluidic platform, which can provide compulsive droplet collisions, was developed to imitate the droplet coalescence process in the early stages of emulsification. Microscope videos showed the variations in the droplet coalescence percentage, d...

Single particle tracking with a wide field microscope is used to study the solid liquid interface between the viscous liquid tetrakis(2-ethylhexoxy)-silane and a silicon dioxide surface. Silicon dioxide nanoparticles (5 nm diameter) marked with the fluorescent dye rhodamine 6G are used as probes. The distributions of diffusion coefficients, obtained by mean squared displacements, reveal heterog...

The director structures, meniscus profile, and defects in free-standing films of the twist grain boundary TGBA and UTGBC* liquid crystals were studied. The films were characterized by a combination of polarizing microscopy and fluorescence confocal polarizing microscopy. Five principal regions of meniscus were distinguished. When film thickness in the meniscus is much smaller then the TGB pitch...

Single particle tracking with a wide field microscope is used to study the solid liquid interface between the viscous liquid tetrakis(2-ethylhexoxy)-silane and a silicon dioxide surface. Silicon dioxide nanoparticles (5 nm diameter) marked with the fluorescent dye rhodamine 6G are used as probes. The distributions of diffusion coefficients, obtained by mean squared displacements, reveal heterog...

The structure of thin-film water on a BaF(2)(111) surface under ambient conditions was studied using x-ray absorption spectroscopy from ambient to supercooled temperatures at relative humidity up to 95%. No hexagonal ice-like structure was observed in spite of the expected templating effect of the lattice-matched (111) surface. The oxygen K-edge x-ray absorption spectrum of liquid thin-film wat...

Liquid membrane processes have attracted many interests in recent years for removal of heavy metals such as cadmium from industrial wastewaters. In this study, a modified hybrid liquid membrane system is introduced. The setup is worked by applying the water-insoluble dioctyl phthalate as the organic solvent. N-octanol and tetra butyl ammonium bromide are added to the organic phase to increase t...