نتایج جستجو برای: modified voltammetric methods
تعداد نتایج: 2077917 فیلتر نتایج به سال:
this study demonstrates the use of a selective and sensitive voltammetric sensor for determination of acetaminophen (ac). this was performed by modifying a glassy carbon electrode with composite film of poly(4-vinylpyridine) and graphene sheet (p4vp/gr-gce). the redox peak currents of ac increased significantly at p4vp/gr-gce. the result was achieved by the synergistic effect of combined elect...
A sensitive adsorptive stripping procedure (square wave adsorptive stripping voltammetry), was developed to study the adsorption property of Eosin-Y dye on a working electrode (HMDE) and its determination in selected samples. In addition, differential pulse polarographic and cyclic voltammetric methods were used to evaluate the electrochemical preliminary studies of Eosin-Y dye. By means of usi...
A multiwall carbon nanotubes-modified carbon paste electrode (MWCNTs/MCPE) was fabricated and used to study the electrooxidation of penicillamine (PA) by electrochemical methods in the presence of methyldopa (MDOP) as a homogeneous mediator. The electrochemical oxidation of PA on the new sensor has been carefully studied. The kinetic parameters such as electron transfer coefficient, α, and cata...
Nitric oxide (NO) has been considered as an important bio-regulatory molecule in the physiological process. All the existing methods often employed for NO measurement are mainly indirect and not suitable for in vivo conditions. In this paper, we report a systematic study of electrocatalytic NO reduction by comparing the redox properties of NO at carbon microelectrodes functionalized by Fe, Mn a...
The Au–Bi binary system electrodeposited on the surface of a glassy carbon electrode exhibits catalytic activity during electrooxidation phenylephrine, paracetamol, and caffeine that enhances peak currents decreases overvoltage in oxidation organic compounds. potential difference between peaks modified is 400 mV for phenylephrine paracetamol 300 caffeine, respectively. possibility simultaneous ...
Voltammetric properties of electrodes made of multiple-walled carbon nanotubes (MWNTs) with different diameters were investigated by cyclic voltammetry. The results indicate that electrodes made of smaller MWNTs exhibit better voltammetric properties. In addition, electrodes made of mixed MWNTs with large diameter distribution possess the best voltammetric properties. The phenomenon can be expl...
Anodic behavior of aripiprazole (ARP) was studied using electrochemical methods. Charge transfer, diffusion and surface coverage coefficients of adsorbed molecules and the number of electrons transferred in electrode mechanisms were calculated for quasi-reversible and adsorption-controlled electrochemical oxidation of ARP at 1.15 V versus Ag/AgCl at pH 4.0 in Britton-Robinson buffer (BR) on gla...
This study investigated the oxidation of ascorbic acid (Vitamin C) using a platinum nanoparticle electrode coated with an iodine monolayer, called a modified electrode. The electrode were grown using the cyclic voltammetry technique and the electrochemical measurements were taken using the cyclic voltammetry and chronoamperometric technique. In the case of platinum nanoparticle electrode modifi...
A new voltammetric sensor for determination of uric acid (UA) by Cuppercomplex- multiwalled carbon nanotube (Cu-complex-CNT) nanocomposite modifiedcarbon paste electrode (CPE) is reported. The electrocatalytic behavior of theCu-complex-CNT nanocomposite modified CPE was studied in pH 2.0 phosphatebuffer solution by chronoamperometry (CA) and cyclic voltammetry (CV) in th...
A novel MnO2 nanorods modified screen-printed electrode was fabricated and used as a voltammetric sensor for Sudan determination. were characterized using Field emission-scanning electron microscopy (FE-SEM). Electrochemical measurements performed cyclic voltammetry (CV), linear sweep (LSV), differential pulse (DPV), chronoammperometry (CA). The on the surface act an excellent catalyst oxidatio...
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