In the past few years multi component reactions have captured the attention of synthetic chemists as they provide  easy  access  to diverse  complex  organic molecules through  carbon -  carbon   and  carbon - heteroatom  bond  formations  in tandem manner with simple easy  to carry out  reaction  conditions in short  time. 1,8-dioxo-octahydroxanthene is a significant class of oxygen containing...

Facile and versatile procedures have been explored for the synthesis of tetrahydropyridines and 2,3-dihydroquinazolin-4(1H)-ones. These protocols employ the one-pot multi-component condensation of arylaldehydes and aromatic amines with β-keto esters and isatoic anhydride in chloroacetic acid, respectively. The reactions proceeded smoothly to generate the corresponding products in high yield. We...

INTRODUCTION Hardness is one of the basic properties of dental materials, specially composite resins which is relevant to their polymerization. The aim of this study was to evaluate the effect of light curing distance and the color of clear Mylar strips on surface hardness of Silorane-based (SCR) and Methacrylate-based composite resins (MCR). MATERIALS AND METHODS 40 samples of MCRs (Filtek Z...

The predictive capabilities of Computational Fluid Dynamics (CFD) for combustion systems rely on a proper description the fuel chemistry. growing interest in accurately capturing behavior multi-component mixtures creates additional challenges developing reduced-order chemical kinetics mechanisms small enough to be used CFD. Among suite chemistry reduction approaches available, lumping technique...

In this study, an in-house multi-dimensional code has been developed which simulates the combustion of n-heptane in a Homogeneous Charge Compression Ignition (HCCI) engine. It couples the flow field computations with detailed chemical kinetic scheme which involves the multi-reactions equations. A chemical kinetic scheme solver has been developed and coupled for solving the chemical reactions an...

The purpose of the present study is to present the results of anterior cruciate ligament (ACL) augmentation for patients having rotational instability despite an intact vertical graft in lieu of conventional revision ACL reconstruction. ACL augmentation surgery with a horizontal graft was performed to augment a healed vertical graft on five patients and an accelerated rehabilitation protocol wa...

in this study, an in-house multi-dimensional code has been developed which simulates the combustion of n-heptane in a homogeneous charge compression ignition (hcci) engine. it couples the flow field computations with detailed chemical kinetic scheme which involves the multi-reactions equations. a chemical kinetic scheme solver has been developed and coupled for solving the chemical reactions an...

An efficient method to synthesis the 2H-pyrans using three component reactions of dithiocarbamats, activated acetylenes and isocyanides in water as the solvent is described. In these reactions, synthesis of 2H-pyrans is possible based on the one-pot reaction and without using any catalyst. The mild reaction conditions and high yields of the products exhibit synthetic advantage of these methods.

ABSTRACT. Benzoylacetone (1) underwent a series of multi-component reactions with aromatic aldehydes and malononitrile or ethyl cyanoacetate to produce the pyran derivatives 4a-f. The latter compounds reacted yield condensation products 5a-m. On other hand, reaction 4a-f either diazonium salts 6a-c yielded arylhydrazone 7a-i. adehydes cyclohexan-1,3-dione produced 9a-c. Compound 1 Gewald’s elem...

The free Modelica library THERMOFLUID (see [2] and [11]) was developed for simulation of thermohydraulic applications, both for single-species applications like the water-steam cycle in a thermal power plant and for multi-species applications with gas mixtures. It has demonstrated its flexibility for modeling thermodynamic and process applications in a variety of industrial and academic project...