Nanocrystalline materials, with a grain size of typically < 100 nm, are a new class of materials with properties vastly different from and often superior to those of the conventional coarse-grained materials. These materials can be synthesized by a number of different techniques and the grain size, morphology, and composition can be controlled by controlling the process parameters. In compariso...

With the help of nanocrystalline TiO2, the direct electrochemistry of xanthine oxidase (XOD) was achieved and two pairs of redox waves were observed. The interaction between XOD and nitric oxide (NO) was also investigated. The experimental results reveal that NO can be reduced at a XOD-nano TiO2 film modified electrode. When the NO concentration was low, the reduced product, HNO, would inactiva...

An approach for description of the photoinduced nonlinear optical effects in the superconducting MgB₂:Cr₂O₃ nanocrystalline film is proposed. It includes the molecular dynamics step-by-step optimization of the two separate crystalline phases. The principal role for the photoinduced nonlinear optical properties plays nanointerface between the two phases. The first modified layers possess a form ...

Nanocrystalline NaNO3 enclathrated microporous material with intermediate structure (INT) between the well known zeolites sodalite (SOD) and cancrinite (CAN) can be prepared from aluminosilicate gels under addition of high amounts of NaOH and NaNO3 using low temperature conditions (333 K) within reaction periods of 1 96 h. The nanocrystalline products were characterized by X-ray powder diffract...

This report summarizes the findings of an interlaboratory study (ILS) conducted in 2009-2010 under the auspices of the Versailles Project on Advanced Materials and Standards (VAMAS) Technical Working Area (TWA) 34 (Nanoparticle Populations). The stated objective of this ILS was to assess the “real world” measurement precision and between-laboratory variation for determination of the surface are...

A theoretical model is suggested, which describes a decay of low-angle grain boundaries in deformed nanocrystalline materials (NCMs). In the framework of the model, lattice dislocations that form a low-angle boundary are under the action of the forces owing to external (applied) and internal stresses. The balance of the forces causes the critical shear stress at which a low-angle boundary decay...

NTRODUCTION Silver is well known as an antiseptic agent (silver nitrate and silver sulphadiazine) for ages. However, the delivery system in the form of a salt has been a limiting factor for its successful and widespread biological use. The development of nanochemistry has produced micro fine particles which increase silver's solubility and releases silver ions in concentration of 70-100 ppm. Na...

Titanium oxide (TiO2 , titania) is well-known as an important ceramic material. Due to its versatile optical, electrical and photochemical properties, it has found extensive applications in high-refractive index devices, optical waveguides, photo-catalysts and photovoltaic cells. Particularly, in the form of very fine particles on the scale of ten to hundreds of nanometers, TiO2 , along with ot...

Vapor-liquid-solid (VLS) Si nanotowers were coated with nanocrystalline SiC to form a Si-SiC core-shell composite. Due to a mismatch in the coefficients of thermal expansion (CTE), the Si core was under a compressive stress following the deposition. The composite tower was then cross-sectioned using focused ion beam milling, exposing the Si core. Indentation into the Si showed an increased toug...

Nanocrystalline silver dressings are widely known to be potent antimicrobial and anti-inflammatory agents and have long been used to treat topical wounds. Gold is known to be a strong anti-inflammatory agent and has been used in the treatment of rheumatoid arthritis for >70 years. The purpose of this work was to study the effect of incorporating gold into nanocrystalline silver dressings from a...