A novel tubular NiO nanostructure was synthesized by a facile and low-cost hydrothermal strategy and then further functionalized by decorating α-Fe2O3 nanorods. The images of electron microscopy indicated that the α-Fe2O3 nanorods were assembled epitaxially on the surfaces of NiO nanotubes to form α-Fe2O3/NiO nanotubes. As a proof-of-concept demonstration of the function, gas sensing devices we...

For decades Ni has been known as an electrocatalyst for the oxygen evolution reaction (OER), however, crucial role that Fe plays in enhancing electrocatalytic activity of still requires deeper investigation and understanding. In this work, we shed some light on by studying structural different Ni-based electrocatalysts upon electrolytic addition quantities Fe. Colloidal NiO, well Ni, NiO NiNiO ...

Oxidation of solid metal nanoobjects is a versatile approach to generating hollow metal oxide nanostructures. The mechanism for the solid-to-hollow conversions has been attributed to the Kirkendall effect, which describes an unbalanced interdiffusion of a thermal diffusion couple. When a metal nanoobject is exposed to oxygen at elevated temperatures, the outward diffusion of the metal cations i...

The colloidal behavior of nickel aqueous suspensions is studied and compared to that of NiO suspensions. Under acidic conditions, nickel readily dissolves, but no dissolution takes place at basic pH. Zeta potential is studied as a function of pH, showing that the isoelectric point (IEP) occurs at pH 3.5-4. Above the IEP there is a zeta potential plateau, which is associated to the predominance ...

A NiO-MgO layered, binary thin oxide film has been prepared on a Mo(100) surface and characterized byAuger electron spectroscopy (AES), low energy electron diffraction (LEED) and high-resolution electron energy loss spectroscopy (HREELS or EELS). NiO grows epitaxially on a 20-monolayer (ML) MgO(100) film supported on the Mo(100) surface. At a NiO coverage of <1.8 monolayer, a new surface or int...

Nanoporous nickel oxide (NiO x ) has been deposited with two different procedures of sintering (CS and RDS). Both samples display solid state oxidation at about 3.1 V vs Li+/Li. Upon sensitization of CS/RDS NiO x with erythrosine b (ERY), nickel oxide oxidation occurs at the same potential. Impedance spectroscopy revealed a higher charge transfer resistance for ERY-sensitized RDS NiO x with res...

Thin films of NiO were fabricated in air by surface-oxidation epitaxy (SOE) on biaxially-textured Ni substrate, for use as buffer layers for YBCO coated conductors. The surface-oxidation conditions such as the temperature and the reaction time, as well as the cooling rate, playa determining role in the process of epitaxial growth of the NiO layer. A continuous, biaxially-aligned textured NiO la...

p-type NiO nanofibers have been synthesized from a simple electrospinning and sintering procedure. For the first time, p-type nanofibers have been electrospun onto a conductive fluorine doped tin oxide (FTO) surface. The properties of the NiO nanofibers have been directly compared to that of bulk NiO nanopowder. We have observed a p-type photocurrent for a NiO photocathode fabricated on an FTO ...