Nitrogen management continues to be diffi cult due to transformations of nitrogen fertilizers that are possible when applied to soil and the uncertainties of weather (Cabrera et al., 2008). Nitrogen (N) fertilizer in the form of urea is subject to ammonia volatilization through the activity of the urease enzyme found ubiquitously in soil (Kissel et al., 2008). Nitrate fertilizer is subject to l...

3.1. Carbon−Nitrogen Bond Formation 14 3.1.

It is shown that the N-(p-ethoxyphenyl) group on beta-lactams can be oxidatively removed by ceric ammonium nitrate in good yield. Fourteen new N-(p-ethoxyphenyl)-2-azetidinones 8a-n were synthesized through standard [2+2] ketene-imine cycloadditions (Staudinger reaction). Treatment of these compounds with ceric ammonium nitrate yielded the N-dearylated 2-azetidinones 9a-n in good to excellent y...

Ammonium Nitrate (AN) prilling Process is nonlinear and non stationary in nature. Due to uncertainty created by nonlinear conditions like temperature rise due to exothermic reaction in the neutraliser, level in the evaporator, velocity of the cooling air in prilling tower, temperature and moisture content of prills and size of the prills. Due to these difficulties the degree of automation is qu...

Fog composition and deposition fluxes of fog water and fog solutes were measured in six radiation fog events in San Joaquin Valley, California during winter 1998/1999. Measurements made at 2 hr intervals with 0.30 m2 and 0.06 m2 Teflon deposition plates yielded excellent reproducibility (relative standard deviations of 3.8–6.0%) for water, nitrate, sulfate and ammonium. Water fluxes measured at...

In the crystal structure of the title salt, C7H12N2 (2+)·2NO3 (-), the nitrate ions are located in the vicinity of the protonated amine groups, accepting strong N-H⋯O hydrogen bonds. Each ammonium group is involved in a total of three such inter-actions with neighbouring nitrate ions, generating a three-dimensional network. In addition, there are π-π inter-actions between the aromatic rings of ...

Using Agrobacterium rhizogenes due to create hairy roots is a useful method to product secondary metabolites in many medicinal plants. The transgenic hairy roots were induced from Peganum multisectum (Maxim) Bobrov a medicinally important species, by infecting leaf and stem explant with wild type Agrobacterium rhizogenes strain ATTCC 15834, which led to the induction of hairy roots from 19% of ...

A series of 2-arylquinazolines have been synthesized in moderate to excellent yields by one-pot tandem reaction of (2-aminophenyl)methanols, aldehydes and ceric ammonium nitrate (CAN). The utility of this transformation was demonstrated by its compatibility with a wide range of functional groups. Thus, the method represents a simple and practical procedure to access 2-arylquinazolines.