The prediction of phase equilibria for hydrocarbon/water blends in separators, is a subject considerable importance chemical processes. Despite its relevance, there are still pending questions. Among them, the correct number phases. While stability analysis using Gibbs Free Energy mixing and NRTL model, provide good understanding with calculation issues, when HYSYS V9 Aspen Plus software, this ...

The first and second law of thermodynamics are applied to an ionic-liquid (IL) based absorption refrigeration system for high power electronics cooling. The IL is a salt in a liquid state usually with an organic cation and inorganic anion. It provides an alternative to the normally toxic working fluids used in the chemical compression loop, such as ammonia in conventional absorption systems. Th...

The thermodynamics of electrolyte solutions has been investigated by many scientists throughout the last century. While several theories have been presented, the most popular models for the electrostatic interactions are based on the Debye− Hückel and mean spherical approximation (MSA) theories. In this paper we investigate the differences between the Debye− Hückel and the MSA theories, and com...

Objectives : Acid gases such as carbon dioxide (CO<sub>2</sub>) and hydrogen sulfide (H<sub>2</sub>S) that cause global warming are mainly generated in chemical processes. As a technology for reducing acid gas, the post-combustion capture process is representative. Aqueous alkanolamine solution, which used absorption process, most representative absorbent. Thermodynamic ...

The extension of the translated–consistent Peng–Robinson (tc-PR) equation state (EoS) to mixtures has been investigated. For this purpose, advanced EoS/aresE,γ mixing rules are used combine tc-PR EoS with residual part an activity coefficient model chosen among Wilson, nonrandom two-liquid (NRTL), and universal quasi-chemical (UNIQUAC) models. performances three resulting versions compared agai...

The extension of the translated–consistent Peng–Robinson (tc-PR) equation state (EoS) to mixtures has been investigated. For this purpose, advanced EoS/aresE,? mixing rules are used combine tc-PR EoS with residual part an activity coefficient model chosen among Wilson, nonrandom two-liquid (NRTL), and universal quasi-chemical (UNIQUAC) models. performances three resulting versions compared agai...