The authors obtain, in the Laplace transform space, the exact analytic solution for the Green function and survival probabilities for the excited-state diffusion-influenced reversible geminate reaction, A*+B <==> C*+D, with two different lifetimes and in the presence of an added quenching process. This extends a previous investigation by Popov and Agmon [J. Chem. Phys. 117, 5770 (2002)] of the ...

The silicon photomultiplier (SiPM) is a promising semiconductor device for low-level light detection. The recovery time, or the photon-counting rate of the SiPM is essential for high-flux photon detection in such applications as photon counting computer tomography (CT). A SiPM with epitaxial quenching resistors (EQR SiPM) has advantages in fabricating small APD microcells connected in series wi...

Experiments measuring contact formation between probes in disordered chains provide information on the fundamental time scales relevant to protein folding. However, their interpretation usually relies on one-dimensional (1D) diffusion models, as do many experiments probing a single distance. Here, we use all-atom molecular simulations to capture both the time scales of contact formation, as wel...

It has been reported that the cooperative binding of calcium ions indicated a local conformational change of the human cytosolic phospholipase A2 (cPLA2) C2 domain (Nalefski et al., (1997) Biochemistry 36, 12011-12018). However its structural evidence is less known (Malmberg et al., (2003) Biochemistry 42, 13227-13240). In this letter, life-time decay and fluorescence quenching techniques were ...

Direct Numerical Simulations (DNS) have been conducted to study the response of initially laminar spherical premixed methane–air flame kernels to successively higher turbulence intensities at five different equivalence ratios. The numerical experiments include a 16-species/25-step skeletal mechanism for methane oxidation and a multicomponent molecular transport model. Highly turbulent condition...

Abstract A proper hardening depth is critical to the load-bearing capacity of a part, and heat treatment, including carburizing quenching, can highly determine hardness distribution in part’s surface after manufacturing. This paper proposes ‘hardness prediction parameter optimization’ approach that deploys finite element method (FEM), artificial neural network (ANN), Genetic Algorithm (GA), des...

Insight into the O2 quenching mechanism of a photosensitizer (static or dynamic) would be useful for the design of heterogeneous systems to control the mode of generation of 1O2 in water. Here, we describe the use of a photosensitizer, meso-tetra(N-methyl-4-pyridyl)porphine (1), which was adsorbed onto porous Vycor glass (PVG). A maximum loading of 1.1 x 10(-6) mol 1 per g PVG was achieved. Les...

Porous silicon based sensors were tested in the presence of various linear aliphatic alcohols (methanol to n-hexanol) and water in the range of 10-100 ppm by photoluminescence quenching technique. An increasing trend in the degree of quenching was observed with the chain length of alcohols while minimum response was given to water. Sensitivity as high as 80-90% and nearly instant response time ...