Density functional theory calculations are often used to interpret experimental shifts in core level binding energies. Calculations based on gradient-corrected (GC) exchange-correlation functionals are known to reproduce measured core level shifts (CLS) of isolated molecules and metal surfaces with reasonable accuracy. In the present study, we discuss a series of examples where the shifts calcu...

[1] The interdecadal variability of summer precipitation in Beijing from 1724 to 2005 is analyzed using a filter, keeping the true trends at time series ends. A probability distribution, Pearson type III, was applied to the summer precipitation series to estimate the probability of anomalous rainfall. This study includes the correlation between the interdecadal variations of the summer precipit...

Since the early 1990s Pacific Walker circulation shows a multi-decadal strengthening, which contradicts future model projections. Whether this trend, evident in many climate indices especially before 2015 El Niño, reflects coupled ocean-atmosphere response to global warming or negative phase of Decadal Oscillation (PDO) remains debated. Here we show that sea surface temperature trends during 19...

Serra da Estrela Protected Designation of Origin (PDO) cheese is the most famous Portuguese cheese and has a high commercial value. However, the adulteration of production with cheaper/lower-quality milks from non-autochthones ovine breeds compromises the quality of the final product and undervalues the original PDO cheese. A Randomly Amplified Polymorphic DNA (RAPD) method was developed for ef...

Biochemical, volatile and textural profiles during manufacture and ripening were determined in samples of Castelmagno PDO cheese obtained from three different batches in the main artisan cheese plant of Castelmagno PDO production area. At the end of manufacture, samples were characterised by a pH of 6.57% and 52.4% moisture content. The HPLC analysis of organic acids and sugars showed the exhau...

Effective and efficient information management and knowledge sharing has become an essential part of more and more professional tasks in the Product Development Process. Among the varius Knowledge Management technologies, ontologies offer new possibilities for representing, handling and retrieving product related knowledge, and for online collaboration. We conceived a Product Design Ontology (P...

We prepared 0.1 wt%-30 wt% Pd-loaded Co3O4 by a colloidal mixing method and investigated the sensing properties of a Pd-loaded Co3O4 sensor element, such as the sensor response, 90% response time, 90% recovery time, and signal-to-noise (S/N) ratio, toward low nitric oxide (NO) gas levels in the range from 50 to 200 parts per billion. The structural properties of the Pd-loaded Co3O4 powder were ...

Thermal behavior of the complexes Pd2(dppm)2Cl2, Pd2(dppm)2(SnCl3)Cl and Pd2(dppm)2(SnCl3)2 (dppm=bis[diphenylphosphino(methane)], ((C6H5)2PCH2P(C6H5)2) in the solid state and immobilized onto porous Vycor glass was studied. Similar decomposition mechanisms were observed for the solid and immobilized complexes, with a small thermal stabilization upon immobilization. The decomposition products w...

We investigate the application of windowed Fourier frames to the numerical solution of partial differential equations, focussing on elliptic equations. The action of a partial differential operator (PDO) on a windowed plane wave is close to a multiplication, where the multiplication factor is given by the symbol of the PDO evaluated at the wave number and central position of the windowed plane ...

Spherical signals exist in many applications, e.g., planetary data, LiDAR scans and digitalization of 3D objects, calling for models that can process spherical data effectively. It does not perform well when simply projecting into the 2D plane then using planar convolution neural networks (CNNs), because distortion from projection ineffective translation equivariance. Actually, good principles ...