Conical intersections are now known to be involved in a large variety of photochemical transformations. In this paper, we present a simple method for determining the existence of a conical intersection for a given chemical reaction. The method, based on the phase change theorem, is easy to apply, does not require quantum chemical calculations, and uses ground state surface properties only. The ...

The optical gradient force distributions in focal plane of cosh-Gaussian beams with sine-azimuthal variation wavefront and half space phase modulation were investigated. Results show that optical gradient force distributions can be affected considerably by the phase retardation of half-space phase modulation, of a phase parameter that indicates the phase change frequency on an increasing azimut...

We propose an explanation for the onset of oscillations seen in numerical simulations of dense, inclined flows of inelastic, frictional spheres. It is based on a phase transition between disordered and ordered collisional states that may be interrupted by the formation of force chains. Low-frequency oscillations between ordered and disordered states take place over weakly bumpy bases; higher-fr...

By utilizing the phase change properties of vanadium dioxide (VO2), we have demonstrated the tuning of the electric and magnetic modes of split ring resonators (SRRs) simultaneously within the near IR range. The electric resonance wavelength is blue-shift about 73 nm while the magnetic resonance mode is red-shifted about 126 nm during the phase transition from insulating to metallic phases. Due...

The inactivation of Listeria innocua BGA 3532 at subzero temperatures and pressures up to 400 MPa in buffer solution was studied to examine the impact of high-pressure treatments on bacteria in frozen matrices. The state of aggregation of water was taken into account. The inactivation was progressing rapidly during pressure holding under liquid conditions, whereas in the ice phases, extended pr...

Amorphous Ge₂Sb₂Te₅ (GST) alloy, upon heating crystallize to a metastable NaCl structure around 150°C and then to a stable hexagonal structure at high temperatures (≥250°C). It has been generally understood that the phase change takes place between amorphous and the metastable NaCl structure and not between the amorphous and the stable hexagonal phase. In the present work, it is observed that t...

This article presents a comprehensive review of the literature that deal with ventilation and cooling technologies applied to agricultural greenhouses. The representative application of each technology as well as its advantages and limitations are discussed. Advance systems employing heat storage in phase change materials, earth-to-air heat exchangers and aquifer-coupled cavity flow heat exchan...

The Verwey transition in Fe3O4, a complex structural phase transition concomitant with a jump in electrical conductivity by two orders of magnitude, has been a benchmark for charge ordering (CO) phenomena in mixed-valence transition metal materials. CO is of central importance, because it frequently competes with functional properties such as superconductivity or metallic ferromagnetism. Howeve...

In undergraduate optics laboratory, one thing that is not easily achieved is quantitative measurement of optical phase. The reason is that optical phase measurement usually requires expensive interferometers. We demonstrate measurement of relative optical phase shift upon total internal reflection. Total internal reflection, though known by every student of optics, is remembered by 100% reflect...