In the mononuclear title compound, [Ni(C(10)H(9)N(4)O(2)S)(2)(C(12)H(8)N(2))], the Ni(II) atom has a distorted octa-hedral coordination geometry comprising four N atoms from two 4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidate ligands and two N atoms from a 1,10-phenanthroline ligand. In the crystal, mol-ecules are connected into a three-dimensional supra-molecular network via N-H⋯O hydrogen bon...

Reactions of equemolar amounts of lead (II) nitrate and 2,2'- bipyridine o r l , 10- phenanthroline in aqueous methanolicsolution yield crystals of Pb (bipy)(H O)(NO ) (1) or Pb (phen) (H O) (NO ) (2) respectively. Their structures were determined by X-ray crystallography. The method and structure determination is described

In the crystal structure of the title compound, [Zn(C(7)H(10)O(4))(C(12)H(8)N(2))(2)]·6H(2)O, the Zn(II) atom is coordinated by two carboxyl-ate O atoms of a mono-bidentate chelating pimelate anion (pimelic acid is hepta-nedioic acid) and four N atoms of two phenanthroline ligands, forming a considerably distorted octa-hedral ZnN(4)O(2) coordination geometry. The complexes are assembled into a ...

The polymeric title compound, [Cu(C(6)H(2)O(5))(C(12)H(8)N(2))(C(5)H(10)N(2)O)](n), is composed of an infinite chain formed along [100] by linking the (1,3-dimethyl-imidazolin-2-one)(1,10-phenanthroline)copper(II) units with two O atoms of two carboxyl-ate groups of the furan-2,5-dicarboxyl-ate ligand. The Cu(II) atom, which lies on a twofold rotation axis, displays a square-pyramidal coordinat...

In the title mol-ecule, C(24)H(16)N(4)O·H(2)O, the benzene ring of the 1,10-phenanthroline group and that of the 2-phenyl-pyridine group are respectively twisted by 67.9 (1) and 15.3 (3)° from the carbamoyl group defined by the plane of the O=C-N group of atoms. The water mol-ecule is hydrogen bonded to one of the phenanthroline N atoms. In the crystal structure, significant π-π stacking inter-...

In the title complex, [Y(2)(C(5)H(6)O(4))(3)(C(12)H(8)N(2))(2)](n), three glutarate groups and two 1,10-phenanthroline mol-ecules surround the two Y(III) ions. Both Y(III) ions are coordinated by two N atoms from the 1,10-phenanthroline, seven O atoms from five glutarate groups in a distorted tricapped trigonal-prismatic geometry. The Y(III) ions are bridged by glutarate ligands in three modes,...

The title compound, [Ni(C(12)H(8)N(2))(3)](2)[Ag(CN)(2)](3)(NO(3))·4.2H(2)O, crystallizes with two independent [Ni(phen)(3)](2+) cations (phen is 1,10-phenanthroline; both Ni atoms have threefold symmetry and N(6) donor sets), three near-linear [Ag(CN)(2)](-) anions, one nitrate anion (N site symmetry 3) and 4.2 water mol-ecules of crystallization, some of which are disordered. The [Ag(CN)(2)](...

The cationic complex in the structure of the title compound, [Co(Et(2)NCS(2))(2)(C(12)H(8)N(2))]BF(4), has a Co(III) atom with a distorted octa-hedral coordination formed by four S atoms of two diethyl-dithio-carbamate and two N atoms of 1,10-phenanthroline ligands. The crystal structure features head-to-tail stacking of the phenanthroline ligands. The tetra-fluorido-borate anions are positione...