Photochromic Materials. In their Communication (e202214202), Lars Heinke et al. report nanoporous films with oriented arrays of molecular motors for light-controlled adsorption and diffusion.

Photochromic crown compounds, such as monomeric and polymeric crown compounds incorporating spirobenzopyran, spironaphthooxazine, spirobenzothiapyran, Malachite Green, and Crystal Violet moieties, were synthesized for applications in the fields of analytical and separation chemistry. The photochromic crown compounds, especially crowned spirobenzopyran derivatives, were applied to metal ion extr...

The dependence of the photoinduced bending behavior of diarylethene crystals on the ultraviolet light irradiation wavelength was investigated. When irradiated with 365 nm light, a crystal of 1,2-bis(5-methyl-2-phenyl-4-thiazolyl)perfluorocyclopentene (1a) bends toward the incident light. On the other hand, when irradiated with 380 nm light, the crystal of 1a first bends away from the light sour...

Spiropyrans are notable among different classes of photochromic compounds due to their large structural and electronic transformation upon isomerization. In order to parlay the electronic differences associated with the two isomeric forms into a materials based switch, the spiropyran ultimately requires a covalent attachment through a conjugated pathway. In this work a synthetic method was deve...

Cycloreversion processes of three photochromic diarylethene derivatives with extremely low one-photon reaction yields (5.0 x 10(-5) to 1.5 x 10(-2)) were investigated by means of femtosecond and picosecond laser photolysis methods. Femtosecond visible laser photolysis revealed that the excited state of the closed form in these three derivatives decayed into the ground state with 0.7-8 ps time c...

We have developed the first red fluorescent protein, named rsTagRFP, which possesses reversibly photoswitchable absorbance spectra. Illumination with blue and yellow light switches rsTagRFP into a red fluorescent state (ON state) or nonfluorescent state (OFF state), respectively. The ON and OFF states exhibit absorbance maxima at 567 and 440 nm, respectively. Due to the photoswitchable absorban...

The implementation of multiconfigurational quantum chemistry methods into a quantum-mechanics/molecular-mechanics protocol has allowed the construction of a realistic computer model for the sensory rhodopsin of the cyanobacterium Anabaena PCC 7120. The model, which reproduces the absorption spectra of both the all-trans and 13-cis forms of the protein and their associated K and L intermediates,...

purpose: to describe the biometric changes and their effect on intraocular lens (iol) power calculation after trabeculectomy and to compare the accuracy of four formulas namely srk/ii, srk/t, holladay and hoffer q for iol power calculation in these patients. methods: thirty-four eyes of 31 glaucoma patients who were scheduled for primary trabeculectomy were enrolled. a non-contact biometry devi...

purpose: to evaluate the safety, efficacy, stability and predictability of posterior chamber collagen copolymer phakic intraocular lens (piol) implantation to correct myopia and myopic astigmatism in keratoconus-affected patients. methods: uncorrected (ucva) and best-corrected (bcva) distance visual acuity, refraction and complications were evaluated in 22 keratoconic eyes of 14 patients who un...

purpose: to compare visual outcomes and surgical complications of three phakic intraocular lenses (piols); artisan, artiflex and the implantable collamer lens (icl) for correction of moderate to high myopia. methods: in this historical cohort study, 112 myopic eyes that were operated between 2005 and 2010 and implanted with one of these three piols were evaluated (artisan 40 eyes, artiflex 36 e...