The asymmetric synthesis of a chiral, nonracemic π-conjugated system with D2 point group of symmetry, dodecaphenylene 4 is described. In the key step, (−)-sparteineand Cu(II)-mediated oxidation of 2,2′-dilithio-1,1′-biaryls in ether gives the corresponding dimers, tetra-o-phenylenes, in 80% isolated yields and 50–60% ee’s. X-Ray crystallography confi rms the structure of rac-4 and its molecular...