A novel hybrid mesoporous material functionalized with carboxy groups was synthesized by self-assembly of a novel building block consisting of a cubic siloxane unit and a long organic chain with an ester bond and the following hydrolysis of ester bonds, representing a promising approach to designing hybrid structures at both molecular and mesoscopic scales.

Abstract Acidic biotrickling filters (BTF) can be used for simultaneous removal of hydrogen sulfide (H2S) and siloxane from biogas. In this study, the performance a BTF under different acidic pH conditions was investigated. The profile H2S showed that 90% achieved during first 0.4 m height with down-flow Decamethylcyclopentasiloxane (D5) decreased 34.5% to 15.6% when increased 0.88 3.98. Furthe...

We propose the exploitation of a holed-designed poly(dimethyl)siloxane (PDMS) membrane as an innovative microarray spotter. The membrane is fabricated by a simple technological approach and can be reused several times. A good level of reproducibility is found upon spotting fluorescent proteins at different concentrations over large areas.

Poly(3-hexylthiophene)-functionalized siloxane nanoparticles were prepared by a modified Stöber method. The photovoltaic performance of P3HT-nanohybrids with C60 derivative PCBM was evaluated. The device made from 1 : 1 blends of P3HT-NPs:PCBM showed reasonably good photovoltaic performance with a power conversion efficiency of 2.5% under standard test conditions (AM 1.5G, 100 mW cm(-2)).

We introduce a new class of siloxane-based epoxy polymers for thin film optical waveguide applications. The thickness of spun-on films can be controlled by varying either spin speed or viscosity using solvents. Cured films exhibit excellent adhesion to silicon oxide and Al and excellent thermal and chemical stability. Waveguides of ~ 2 micron thickness on silicon oxide exhibit <0.2 dB/cm loss a...

This study was aimed at investigating the internal adaptation of a ceramic (Ceramco II) and two composite resin inlay materials (SureFil and 3M Filtek Z 250) using silicon replica technique as an indicator. Forty-five standard mesial-occlusal-distal (MOD) cavities were prepared into brass moulds by using computer numerically controlled system. Inlays were prepared according to manufacturers' in...

A method for situ preparing a hybrid material consisting of silica nanoparticles (SiO2) attached onto the surface of functionalized graphene nanoplatelets (f-GNPs) is proposed. Firstly, polyacrylic acid (PAA) was grafted to the surface of f-GNPs to increase reacting sites, and then 3-aminopropyltriethoxysilane (APTES) KH550 reacted with abovementioned product PAA-GNPs to obtain siloxane-GNPs, t...

The goal of the study was to characterise chemical interactions between waterlogged archaeological wood and organosilicon compounds applied for its conservation shed lights on mechanism dimensional stabilisation by chemicals. Two alkoxysilanes (methyltrimethoxysilane (3-mercaptopropyl) trimethoxysilane) a siloxane (1,3-bis(diethylamino)-3-propoxypropanol)-1,1,3,3-tetramethyldisiloxane) were sel...

Inorganic nanometer-sized particles (nanoparticles) are attracting attention as reinforcing fillers for use in polymer-nanoparticle composites (nanocomposites) because they improve key characteristics of these composites at a relatively low content (Hussain et al., 2006, Jordan et al., 2005). For example, clay nanoparticles (Usuki et al, 2005), metal oxide nanoparticles such as silica (Rosso et...