Often experimentalists study particulate samples that are nominally monodisperse. In reality, many samples have a polydispersity of 4-10%. At the level of an individual particle, the consequences of this polydispersity are unknown as it is difficult to measure an individual particle size from images of a dense sample. Here we propose a method to estimate individual particle radii from three-dim...

Phenomena characterized by power-law probability distributions abound in nature and the applied sciences. We show that many of these power laws are well described by the Student, or t, distribution, and we discuss the origin of this universality based on three examples (Brownian motion, Knudsen diffusion in rough pores, and bubbly multiphase flow). These case studies are representative for a la...

Polymeric stabilizers have received attention in the preparation of nanostructured systems due to their ability to enhance formulation stability. Considering this, the objective of this work was to prepare poly(ε-caprolactone) nanocapsules using the pullulan as a polymeric stabilizer. The nanocapsules were prepared using the interfacial deposition method of preformed polymers and they were char...

Allyl glycidyl ether, polymerized from potassium alkoxide/naphthalenide initiators under both neat and solution conditions was shown to be a highly-controlled process. In both cases, molar masses (10-100 kg/mol) were determined by the reaction stoichiometry, and low polydispersity indices (1.05-1.33) could be obtained with a full understanding of the dominant side reaction, isomerization of the...

This Letter describes the generation of 2D colloidal lattices in microchannels by coupling the laminar flow of dispersions of spherical colloids and geometrical confinement. We describe a nonequilibrium, convective, mechanism leading to formation of ordered 2D structures of both closed-packed hexagonal and non-closed-packed rhombic symmetries. The number and types of possible lattices is determ...

This work reports that the rheology of ideally monodisperse lambda ( λ $$ \lambda ) phage DNA solutions is extremely sensitive to applied strain in dynamic oscillatory experiments. exhibits nonlinearity at strains far smaller than what observed conventional synthetic polymers. However, it found polydisperse calf thymus does not exhibit extreme sensitivity. By mixing samples with DNA, we correla...