A series including single and mixed Ni-Co aluminates was obtained using the precursor method, with malic acid as a ligand. The malate precursors (polynuclear coordination compounds) were isolated characterized by Fourier Transform Infrared (FTIR), Ultraviolet/Visible/Near (UV–Vis–NIR) spectroscopy, thermal analysis. UV–Vis–NIR spectra of synthesized complex compounds highlighted presence Co2+ N...

Polynuclear coordination clusters can be readily arranged in cluster-based polymers (CCPs) by appropriate bridging linkers. This review provides an overview of our recent developments exploring structurally well-defined Mn/Fe-oxo pivalate and isobutyrate building blocks the formation CCPs assemblies with emphasis on synthetic strategies magnetic properties.

A new click chemistry generated artificial metallonuclease is reported in the Research Article by Andrew Kellett et al. (e202305759). The oxidative DNA damaging properties of a polynuclear copper binding ligand called TC-Thio demonstrated. Copper-TC-Thio binds minor groove genomic and promotes damage via superoxide linked mechanism. inset picture shows ions, bound to ligand, melting into duplex...

Heterometallic trinuclear or pentanuclear complexes aligned as Rh−Pt−M Rh−Pt−M−Pt−Rh (M=Pt, Pd, Cu), respectively, were kinetically and thermodynamically synthesized characterized. These polynuclear complexes, in which three kinds of metals form straight one-dimensional structures with metal–metal bonds, are presented sweet, three-colored, Japanese dango dumplings. More information can be found...