A random channel approach is developed for reaction-diffusion processes in disordered systems. Although the starting point of our research is the kinetic study of the decay and preservation of marine organic carbon, our approach can be used for describing other disordered kinetic catalytic processes with random pathways. We consider a generic catalytic mechanism with two species: a) a catalyst,...

Kinetics of the title reaction has been carried out by studying the reaction spectrophotometrically at 80 oC and pH 5.0 in presence of cationic gemini (alkanediyl-α, ωbis(dimethylhexadecylammonium bromide)) surfactants. The reaction followed first-order kinetics in [Zn(II)-Gly-Tyr]T complex and fractional-order kinetics in [ninhydrin]T. Typical rate constant (kΨ) increase and leveling-off regio...

In this research, Graphene Oxide- Gold nanoparticles (AuNP/GO) were easily fabricated by a redox reaction between GO and chloroauric acid without using any additional reductant and then used to stabilize Pickering emulsions. (AuNP/GO) was investigated by FT-IR spectroscopy. The changes of parameters such as contact time, pH, Amoxicillin initial concentration and temperature were tested and inve...

In this research, Graphene Oxide- Gold nanoparticles (AuNP/GO) were easily fabricated by a redox reaction between GO and chloroauric acid without using any additional reductant and then used to stabilize Pickering emulsions. (AuNP/GO) was investigated by FT-IR spectroscopy. The changes of parameters such as contact time, pH, Amoxicillin initial concentration and temperature were tested and inve...

in the present research work, the kinetics of sunflower oil transesterification reaction in the presence of ba-sr/zsm-5 nanocatalyst which prepared using incipient wetness impregnation method was investigated. the 10wt.%ba-sr/zsm-5 (sr/ba=3/2) nanocatalyst was calcined at 600 °c for 6 h with a heating rate of 3 ºc/min. the experimental conditions were the methanol/oil 9/1molar ratio, reaction t...

Kinetics and a mechanistic investigation of the reaction between dimethyl acetylenedicarboxcylate (DMAD) and saccharin (N-H heterocyclic compound) has been spectrally studied in methanol environment in the presence of triphenylarsine (TPA) as a catalyst. Previously, in a similar reaction, triphenylphosphine (TTP) (instead of triphenylarsine) has been employed as a third reactant (not catalyst) ...

For large and complex reacting systems, computational efficiency becomes a critical issue in process simulation, optimization and model-based control. Mechanism simplification is often a necessity to improve computational speed. We present a novel approach to simplification of reaction networks that formulates the model reduction problem as an optimization problem and solves it using geneti...