When electronically excited CO(a(3)Π) collides with a Au(111) surface, electron emission can be observed with a quantum efficiency of 0.13. We have studied the influence of Ar, Kr and Xe adsorption on the electron emission efficiency resulting from CO(a(3)Π) quenching. Surprisingly, a single monolayer (ML) of rare gas dramatically enhances electron emission. For Ar and Kr bilayers, emission eff...

In this paper, the study of melatonin and 60 meta- and ortho-substituted melatonins is presented. The reaction enthalpies related to the hydrogen atom transfer (HAT), single electron transfer - proton transfer (SET-PT) and sequential proton loss electron transfer (SPLET) have been calculated using DFT/B3LYP method in gas-phase and water. Results show that electron-withdrawing substituents incre...

The direct electrochemistry of human, bovine and porcine cytochrome P450c17 (CYP17) has been examined on an edge-oriented pyrolytic graphite electrode. The recombinant protein was immobilized on an electrode modified with a surfactant to simulate the environment of a biological membrane, and hence physiological electron-transfer conditions. The P450 enzymes all retained 'electron-transfer' acti...

The electrochemical properties of an electrochemical cell defined by two concentric spherical electrodes, separated by a 1 to 20-nm-wide gap, and a freely diffusing electrochemically active molecule (e.g., ferrocene) have been investigated by coupling of Brownian dynamics simulations with long-range electron-transfer probability values. The simulation creates a trajectory of a single molecule a...

We report the construction of a synthetic flavo-heme protein that incorporates two major physiological activities of flavoproteins: light activation of flavin analogous to DNA photolyase and rapid intramolecular electron transfer between the flavin and heme cofactors as in several oxidoreductases. The functional tetra-alpha-helix protein comprises two 62-aa helix-loop-helix subunits. Each subun...

the dye-sensitized solar cells (dssc) have been regarded as one of the most promising new generation solar cells. tremendous research efforts have been invested to improve the efficiency of solar energy conversion which is generally determined by the light harvesting efficiency, electron injection efficiency and undesirable electron lifetime. in this review, various characteristics of dye-sensi...

Nowadays there are several technologies used for flat panel displays (FPDs) and the development of FPDs with enhanced energy efficiency and improved display quality is strongly required. Field emission displays (FEDs) have been considered as one of the most promising next generation flat panel display technologies due to their excellent display performance and low energy consumption. For the de...