We have fabricated high quality sol-gel derived silicate and aluminoborosilicate thin films deposited on silicon substrates. From capacitance vs voltage measurements we observe low interface trap densities (<10H/cm2eV) and very low densities of slow interface state (<101~ 2) in most films investigated. We have been able to make significant improvements over previous sol-gel derived oxides on si...

The paper describes development of a sol-gel based immunoaffinity method for the steroid hormone levonorgestrel (LNG) and the effects of changes in the sol-gel matrix format on the activity of the entrapped antibodies (Abs) and on matrix structure. The best sol-gel format for Ab entrapment was found to be a tetramethoxysilane (TMOS) based matrix at a TMOS:water ratio of 1:8, containing 10% poly...

Microencapsulation has become a hot topic in chemical research. Technology mainly used for control release and protection purposes. The sol-gel micro encapsulation approach for fragrance and aroma in porous silica-based materials leads to sustainable odorant and flavored materials with novel and unique beneficial properties. Sol-gel encapsulation of silica based micro particles considered econo...

As an attractive alternative to organic and silica monoliths, hybrid organic-inorganic monolith somewhat combines the advantages of them, such as high surface area, excellent mechanical strength, and thermal stability. We have reviewed the preparation and application of hybrid monoliths in 2011 and 2013. The preparation approaches have been mainly summarized into three categories: (1) common so...

We report on photochemical reactions in the fluorinated sol–gel hybrid materials doped with a photolocking agent consisting of 3-trimethoxysilylpropyl methacrylate (MPTS), heptadecafluorodecyltrimethoxysilane (PFAS), zirconium n-propoxide (ZPO), and methacrylic acid (MAA). We investigated the effect of the types and density of the photoinitiator, UV fluence, and the illuminating wavelength regi...

An all-aqueous sol-gel method for encapsulation of bacterial cells in porous silicate matrices towards the development of a biosensor is described. The sol-gel encapsulation of cells is achieved at room temperature and neutral pH. Furthermore, use of sodium silicate as precursor avoids generation of alcohol that can be detrimental to cells in contrast to the traditional alkoxide sol-gel encapsu...

We successfully synthesized two different structures, silica nanospheres and porous polymer membranes, via nanophase separation, based on a sol-gel process. Silica sol, which was in situ polymerized from tetraorthosilicate, was used as a precursor. Subsequently, it was mixed with a polymer that was used as a matrix component. It was observed that nanophase separation occurred after the mixing o...

Bioencapsulation has been a promising technique for various biotechnological and medical applications. Nevertheless, when encapsulated, the activity of the encapsulated biologicals is usually reduced due to diffusional resistance and use of organic solvents in the process. Here, we developed a sol–gel electrospinning technique to encapsulate a bacterium, Escherichia coli expressing a biocatalys...