The effects of impurities on the intergranular penetration of Bi based liquids in polycrystalline Ni at 700 C were systematically investigated. In comparison with a nominally pure Ni (99.9945%), the presence of a total amount of <0.5 at.% impurities of Mn, Fe and Si in the Ni increased the penetration length by six times when a near-equilibrium Bi–Ni liquid was applied; when an initially pure B...

in this work, a more accurate prediction of liquid evaporation flux has been achieved. the statistical rate theory approach, which is recently introduced by ward and fang and exact estimation of vapor pressure in the layer adjacent to the liquid–vapor interface have  been used for prediction of this flux. firstly, the existence of an equilibrium layer adjacent to the liquid-vapor interface is c...

Wax formation in hydrocarbon fluids at low temperatures is one of the harassing problems faced by the petroleum industry. The prevention of wax formation, the production of diesels more resistant at low temperatures and the design of new and better additives requires a good understanding of the crystallisation behaviour of the paraffin molecules. Better experimental techniques to study the wax ...

A two-dimensional lattice Boltzmann-cellular automaton model is coupled with the CALPHAD (Calculation of Phase Diagrams) method for simulating dendritic growth during ternary alloy solidification with convection. In the model, the kinetics of dendritic growth is determined by the difference between the equilibrium liquidus temperature and the actual temperature at the solid/liquid interface, in...

The finite solid–liquid interface width in phase field models results non-equilibrium effects, including solute trapping. Prior modeling has shown that this extra degree of freedom, when compared to sharp-interface models, trapping is well captured realistic parameters, such as width, are employed. However, increasing the which desirable for computational reasons, leads artificially enhanced th...

Phase equilibrium calculations at high pressures have been a continuous challenge for scientists and engineers. Traditionally, this task has been performed by solving a system of nonlinear algebraic equations originating from isofugacity equations. The reliability and accuracy of the solutions are strongly dependent on the initial guess, especially due to the fact that the phase equilibrium pro...

We present results of experiments on mixtures of olivine tholeiite and mantle harzburgite, at 5 kb and 1050-1150°C, under conditions of controlled hydrogen fugacity. The basalt end-member was Kilauea 1921 olivine tholeiite + 3 wt.% H2O, and the harzburgite end-member was a mixture of olivine and orthopyroxene mineral separates made from a mantle-derived lherzolite xenolith. The experiments on m...

various basidiomycetes and deuteromycetes, grown in liquid and solid culture media, were compared for their laccase-producing ability and for the inducing effect of soil and agricultural residues on laccase production. laccase activity in extracts of all solid media was higher than that of the liquid media. in liquid cultures, fungal laccase activity in ex-tracts of pea (pisum sativum) straw-tr...

We study the two-dimensional dynamics of a droplet on an inclined, nonisothermal solid substrate. We use lubrication theory to obtain a single evolution equation for the interface, which accounts for gravity, capillarity, and thermo-capillarity, brought about by the dependence of the surface tension on temperature. The contact line motion is modeled using a relation that couples the contact lin...

a mathematical model of sorption of zirconium and hafnium cations mixture and elution of these ions from a cation exchange resin bed is developed. sulfuric acid is selected as the eluent for selective separation of zr and hf in a packed bed of dowex cation exchange resin. the column model is a dispersed plug flow model,and assumed to consist of randomly packed synthetic and spherical resin bead...