Carbon-coated SnO(2) nanorod array directly grown on the substrate has been prepared by a two-step hydrothermal method for anode material of lithium-ion batteries (LIBs). The structural, morphological and electrochemical properties were investigated by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and electrochemical measurement. Wh...

The development of lithium–air batteries is plagued by a high potential gap (>1.2V) between charge and discharge, and poor cyclability due to the drastic phase change of O2 (gas) and O (condensed phase) at the cathode during battery operations. Here we report a cathode consisting of nanoscale amorphous lithia (nanolithia) confined in a cobalt oxide, enabling charge/discharge between solid Li2O/...

Structural degradation and low conductivity of transition-metal oxides lead to severe capacity fading in lithium-ion batteries. Recent efforts to solve this issue have mainly focused on using nanocomposites or hybrids by integrating nanosized metal oxides with conducting additives. Here we design specific hierarchical structures and demonstrate their use in flexible, large-area anode assemblies...

High energy and safe electrochemical storage are critical components in multiple emerging fields of technologies. Rechargeable lithium-metal batteries are considered to be promising alternatives for current lithium-ion batteries, leading to as much as a 10-fold improvement in anode storage capacity (from 372 to 3860 mAh g-1). One of the major challenges for commercializing lithium-metal batteri...

When testing the electrochemical performance of metal oxide anode for lithium-ion batteries (LIBs), binder played important role on the electrochemical performance. Which binder was more suitable for preparing transition metal oxides anodes of LIBs has not been systematically researched. Herein, five different binders such as polyvinylidene fluoride (PVDF) HSV900, PVDF 301F, PVDF Solvay5130, th...

Lithium, a silver-white alkali metal, with significantly high energy density, has been exploited for making rechargeable lithium-ion batteries (LiBs). They have become one of the main storage solutions in modern electric cars (EVs). Cobalt, nickel, and manganese are three other key components LiBs that power vehicles Neodymium dysprosium, two rare earth metals, used permanent magnet-based motor...

Understanding reactions at the electrode/electrolyte interface (EEI) is essential to developing strategies to enhance cycle life and safety of lithium batteries. Despite research in the past four decades, there is still limited understanding by what means different components are formed at the EEI and how they influence EEI layer properties. We review findings used to establish the well-known m...

We have studied stability of lithium-manganese oxides using density functional theory in the local density and generalized gradient approximation ~GGA!. In particular, the effect of spin-polarization and magnetic ordering on the relative stability of various structures is investigated. At all lithium compositions the effect of spin polarization is large, although it does not affect different st...