Based on the adsorption of Fe(EDTA)- on a chitosan-coated glassy carbon electrode, a second-derivative square-wave voltammetry for the determination of the EDTA species in water samples was investigated. The measuring range of EDTA was from 6.0 x 10(-7) to 5.0 x 10(-5) mol/L with a correlation coefficient of 0.998 and a detection limit of 2.8 x 10(-7) mol/L. The relative standard deviation was ...

Redox behavior of midazolam was studied at a glassy carbon electrode in various buffer systems, supporting electrolytes and pH using differential pulse, square-wave and cyclic voltammetry. Based on its reduction behavior, a direct differential pulse voltammetric method has been developed and validated for the determination of midazolam in parenteral dosage. Three well-defined peaks were observe...

Nitrogen doped diamond-like carbon (N-DLC) thin films were prepared on n-Si substrates using a filtered cathodic vacuum arc deposition method. Square wave anodic stripping voltammetry (SWASV) was used to trace Pb and Cu in a neutral KCl solution with pH 7. Stripping voltammograms of Pb and Cu were analyzed in terms of metal concentration, deposition time and deposition potential. The SWASV resu...

The cathodic reduction of SiO2 in KCl-CaCl2-NaCl-MgCl2 melt was studied using tungsten wires as working electrodes. The results of cyclic voltammetry square wave voltammetry and chronopotentiometry showed that the cathodic deposition of silicon is a quasi-reversible diffusion-controlled reaction, followed by a four electrons transfer step. The results of current reversal chronopotentiometry and...

The comparison between the response corresponding to a simple charge transfer taking place at an electroactive monolayer with that of an electrocatalytic process at a modified electrode are presented by using the multipulse potential techniques cyclic staircase voltammetry (CSCV) and cyclic square wave voltammetry (CSWV). General analytical and explicit equations for the I E responses have been...

Herein is reported the preparation of a new triphenylamine derivative, the tris( ́4-formylbiphenyl-4-yl) amine (TFBA). This compound exhibits optoelectronic properties suitable for its use in Dye-Sensitized Solar Cells (DSSCs) and light emitting diodes. The electrochemical properties were studied by cyclic voltammetry (CV) and square wave voltammetry (SWV). At the same time, the symmetrical chem...

In this work, we report for the first time the use of tungsten oxide (WOx) as catalyst support for Au toward the direct electrooxidation of glucose. The nanostructured WOx/Au electrodes were synthesized by means of laser-ablation technique. Both micro-Raman spectroscopy and transmission electron microscopy showed that the produced WOx thin film is amorphous and made of ultrafine particles of su...