The quadrupolar and octupolar cyano triphenylamines shows symmetry broken dipolar charge transfer state, however, its stability can be controlled by the rotation of N-C bond of amino and phenylene moiety.

A series of biaxial V-shaped, shape-persistent molecules has been synthesised by stepwise coupling of phenylene ethynylene arms to an oxadiazole bending unit. Studies of their thermotropic nematic phases point to phase biaxiality.

We have demonstrated the layer-by-layer growth, via a urea coupling reaction between two bifunctional molecules, ethylenediamine and 1,4-phenylene diisocyanate, to form an ultrathin film on Ge(100)-2 x 1 at room temperature under vacuum conditions. The initial adsorption and subsequent growth of each layer was studied with multiple internal reflection Fourier transform infrared (MIR-FTIR) spect...

A series of bis-BODIPYs 1-6 bridged via thiophene, furan, N-alkylcarbazole, triphenyl-amine, para- and meta-phenylene groups have been synthesized and characterized by various spectroscopic techniques. The change in the spectroscopic properties of bis-BODIPYs upon varying the size of spacers was studied. X-ray crystal structures of three bis-BODIPYs containing triphenylamine, para- and meta-phe...

A mono-6-O-propargyl permethylated beta-cyclodextrin, 3, has been prepared by two synthetic routes as a versatile building block for the construction of cyclodextrin dimers and trimers with a core junction which is potentially electron conducting. Glaser-Hay coupling of 3 gave beta-cyclodextrin dimer 6, and Pd(0)-catalysed coupling allowed the preparation of a cyclodextrin dimer with a 1,4-phen...

We have studied the effects of using a composite fabricated from carbon nanotubes and a host polymer, poly~m-phenylene-vinylene-co-2,5-dioctyloxy-p-phenylene-vinylene! ~PmPV!, as an electron-transport layer in organic light-emitting diodes. Double layer devices using this composite as an electron-transport layer, triple layer devices with a composite electron-transport layer, and poly~9-vinylca...

A prototype of a neutral Re-based metallacyclic rotor, assembled in a one-step process, possesses a para-phenylene rotor that rotates in solution with respect to the stator.

Two types of enantioselective [2 + 2 + 2] cycloadditions of triynes using chiral rhodium catalysts are disclosed. The intramolecular reaction of ortho-aminophenol-tethered triynes provides chiral tripodal compounds. Consecutive interand intramolecular reactions of ortho-phenylene-tethered triynes provide chiral tetraphenylenes.

Bichromophoric molecules can support two spatially separated excited states simultaneously and thus provide novel pathways for electronic state relaxation. Exciton fission, where absorption of a single photon leads to two triplet states, is a potentially useful example of such a pathway. In this paper, a detailed study of exciton fission in three novel phenylene-linked bis(tetracene) molecules ...

Geometric optical reflectance models provide a physical linkage between image data and forest structure. We developed a “Multiple-Forward-Mode” pseudoinversion modeling approach to produce structural lookup tables for Landsat Thematic Mapper images before and after 1993 partial harvests in New Brunswick Canada. Modeling results validated for stand density, crown radius, and stem counts enabled ...